A novel Moo(V) oligophosphate built up of di- and triphosphate groups:: CS(MoO)4(P2O7)2(P3O10)

被引：5

作者：

Leclaire, Andre ^{[1
]}

Raveau, Bernard ^{[1
]}

机构：

[1] CNRS, Lab CRISMAT, ENSICAEN, UMR 6508, F-14050 Caen, France

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 2006年 / 179卷 / 08期

关键词：

caesium molybdenum phosphate; diphosphates mixed to triphosphates; molybdenum (V) phosphate; three-dimensional framework;

D O I：

10.1016/j.jssc.2006.04.037

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A Mo(V) oligophosphate, built up of di and triphosphate groups, CS(MoO)(4)(P2O7)(2)(P3O10) has been synthesized for the first time. This compound crystallizes in the triclinic P-1 space group with a = 9.411(1)angstrom, b = 10.754(1)angstrom, c = 12.517(1)angstrom, alpha = 94.534(6)degrees, beta = 102.520(6)degrees, gamma = 103.663(4)degrees. This original structure can be described by the association of MoO6 octahedra, MoP2O11 units built up of one P2O7 group sharing two apices with the same MoO6 octahedron, and triphosphates groups P3O10. The resulting tridimensional framework forms large S-shaped tunnels running along c where the Cs+ cations are located. (c) 2006 Elsevier Inc. All rights reserved.

引用

页码：2433 / 2437

页数：5

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