Radiation, Crystallization, and Physical Properties of Cadmium Borate Glasses

被引:65
|
作者
El-Rehim, A. F. Abd [1 ,2 ]
Zahran, H. Y. [1 ,2 ]
Yahia, I. S. [1 ,2 ]
Makhlouf, Sayed A. [3 ]
Shaaban, Kh. S. [4 ]
机构
[1] King Khalid Univ, Fac Sci, Phys Dept, POB 9004, Abha 61413, Saudi Arabia
[2] Ain Shams Univ, Fac Educ, Phys Dept, POB 5101, Cairo 11771, Egypt
[3] Assiut Univ, Fac Sci, Phys Dept, PO 71452, Assiut, Egypt
[4] Al Azhar Univ, Fac Sci, Chem Dept, PO 71452, Assiut, Egypt
关键词
SEM; Mechanical; Glass-ceramics; Radiation; METAL OXIDE GLASSES; INTERVENTIONAL RADIOLOGY; OPTICAL INVESTIGATIONS; PROTECTION; DOSIMETRY; BEHAVIOR;
D O I
10.1007/s12633-020-00798-3
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The melt-quenching method has been used to fabricate Na2B4O7 - CdO glass system. The XRD diffractometer procedure was used to check the status of these samples. Inter-ionic distance (R-i) between Cd-Cd, Polaron radius r(p), and inter-nuclear distance r(i) reduced with Cd content due to reducing molar volume. Ionicity I-b decreased and covalent glass character increased as CdO in the glass matrix increases. As the CdO contents increase, the values of T-g, T-c, and T-P have been increased. All expected phases are displayed in the XRD patterns. SEM has studied the morphology of the vitreous ceramic. It has been noted that the velocities and elastic modulus of glass-ceramics samples are increased. The structural nature of the developed phase was monitored in spectroscopic FT-IR investigations of the glass-ceramic samples. Mass attenuation Coefficient (mu/rho) increases with CdO-content increase. The Z(eff) values increase gradually at higher energy because of X-ray K-edges. Hence, the increase in CdO content can be developed the gamma -radiation. According to our data, G7 is the best sample for shielding properties.
引用
收藏
页码:2289 / 2307
页数:19
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