Highly enhanced durability of a graphitic carbon layer decorated PtNi3 alloy electrocatalyst toward the oxygen reduction reaction

被引:39
作者
Sun, Kui [1 ,2 ]
Li, Jia [1 ,2 ]
Wang, Feng [1 ,2 ]
He, Wenxiang [1 ,2 ]
Fei, Minfei [1 ,2 ]
Lu, Zhenda [1 ,2 ]
Zhang, Huigang [1 ,2 ]
Liu, Jianguo [1 ,2 ,3 ]
Zou, Zhigang [1 ,2 ,3 ]
机构
[1] Nanjing Univ, Jiangsu Key Lab Nano Technol, Natl Lab Solid State Microstruct, Coll Engn & Appl Sci, 22 Hankou Rd, Nanjing 210093, Jiangsu, Peoples R China
[2] Nanjing Univ, Collaborat Innovat Ctr Adv Microstruct, 22 Hankou Rd, Nanjing 210093, Jiangsu, Peoples R China
[3] Kunshan Sunlaite New Energy Co Ltd, 1666 South Zuchongzhi Rd, Kunshan 215347, Jiangsu, Peoples R China
基金
中国国家自然科学基金; 中国博士后科学基金;
关键词
FUEL-CELLS; LOW-TEMPERATURE; PT-NI; NANOPARTICLES; SEGREGATION; CHALLENGES; ETHANOL; FE; CO;
D O I
10.1039/c9cc02510c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The durability issue of a carbon supported PtNi3 alloy catalyst (PtNi3/C) under acidic conditions has been solved by introducing an N-doped graphitic carbon (NGC) layer to coat the surface of the PtNi3/C catalyst. The as-prepared PtNi3/C@ NGC catalyst exhibits superior durability, being able to undergo 10 000 voltage cycles with negligible activity decay.
引用
收藏
页码:5693 / 5696
页数:4
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