Continuous Head-to-Tail Depolymerization: An Emerging Concept for Imparting Amplified Responses to Stimuli-Responsive Materials

被引：100

作者：

Phillips, Scott T. ^{[1
]}

DiLauro, Anthony M. ^{[1
]}

机构：

[1] Penn State Univ, Dept Chem, University Pk, PA 16802 USA

来源：

ACS MACRO LETTERS | 2014年 / 3卷 / 04期

基金：

美国国家科学基金会;

关键词：

CARBON-DIOXIDE; INITIATED DEPOLYMERIZATION; TRIGGERING EVENT; DEGRADATION; POLYMERS; DENDRIMERS; RELEASE; POLYCARBONATES; MICROCAPSULES; CYCLIZATION;

D O I：

10.1021/mz5000784

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Polymers that depolymerize continuously and completely from head-to-tail when a reaction-based detection unit is cleaved from the polymer provide both selective and amplified responses, a rare combination, to stimuli-responsive polymeric materials. This Viewpoint contextualizes this new class of depolymerizable polymers and outlines the key areas for growth and innovation.

引用

页码：298 / 304

页数：7

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