Studies on the preparation of multi-monomer grafted PP by one-step extrusion and the blends with PVC

被引:9
作者
Hou, L. L. [1 ]
Zhao, M. [2 ]
机构
[1] Hyflux Grp Co, Hydrochem S PTE LTD, Singapore 339339, Singapore
[2] Chinese Peoples Armed Police Acad, Dept Fire Technol, Hebei 065000, Peoples R China
来源
EXPRESS POLYMER LETTERS | 2008年 / 2卷 / 01期
关键词
polymer blends and alloys; multi-monomer grafted; polypropylene; poly(vinyl chloride); compatibility;
D O I
10.3144/expresspolymlett.2008.4
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Firstly, a novel grafted polypropylene (PP) was prepared by one step free-radical melt grafting method in a single-screw extruder. It was shown that the addition of St to the melt-grafting system as a comonomer could significantly enhance the grafting degree of MMA onto PP and reduced the degradation of PP matrix by means of FTIR and MFR tests, respectively. Then, the extruded multi-monomer grafted PP, as a component, was directly blended with poly(vinyl chloride) (PVC), denoted as gPP/PVC. The corresponding improved compatibility was examined. Due to the addition of gPP the tensile strengths of gPP/PVC blends increased significantly in comparison to pure polypropylene/poly(vinyl chloride) blends (PP/PVC), while the impact strengths remained unchanged. The DSC results also suggested that the compatibility of PP/PVC blends were improved largely.
引用
收藏
页码:19 / 25
页数:7
相关论文
共 22 条
[1]  
BYONG JK, 2004, J APPL POLYM SCI, V91, P1983
[2]  
Cartier H, 1998, J POLYM SCI POL CHEM, V36, P2763, DOI 10.1002/(SICI)1099-0518(19981115)36:15<2763::AID-POLA13>3.0.CO
[3]  
2-Y
[4]  
Cartier H, 1998, J POLYM SCI POL CHEM, V36, P1053, DOI 10.1002/(SICI)1099-0518(199805)36:7<1053::AID-POLA3>3.0.CO
[5]  
2-3
[6]   Melt grafting of glycidyl methacrylate onto polypropylene and reactive compatibilization of rubber toughened polypropylene [J].
Chen, LF ;
Wong, B ;
Baker, WE .
POLYMER ENGINEERING AND SCIENCE, 1996, 36 (12) :1594-1607
[7]   POLYPROPYLENE-GRAFT-POLYCAPROLACTONE - SYNTHESIS AND APPLICATIONS IN POLYMER BLENDS [J].
CHUNG, TC ;
RHUBRIGHT, D .
MACROMOLECULES, 1994, 27 (06) :1313-1319
[8]   Synthesis of functional polyolefin copolymers with graft and block structures [J].
Chung, TC .
PROGRESS IN POLYMER SCIENCE, 2002, 27 (01) :39-85
[9]  
Ciardelli F, 2000, POLYM ADVAN TECHNOL, V11, P371, DOI 10.1002/1099-1581(200008/12)11:8/12<371::AID-PAT984>3.0.CO
[10]  
2-Y