P84/ZCC Hollow Fiber Mixed Matrix Membrane with PDMS Coating to Enhance Air Separation Performance

被引:27
|
作者
Widiastuti, Nurul [1 ]
Gunawan, Triyanda [1 ]
Fansuri, Hamzah [1 ]
Salleh, Wan Norharyati Wan [2 ]
Ismail, Ahmad Fauzi [2 ]
Sazali, Norazlianie [1 ,3 ]
机构
[1] Inst Teknol Sepuluh Nopember, Fac Sci & Data Analyt, Dept Chem, Surabaya 60111, Indonesia
[2] Univ Teknol Malaysia, Adv Membrane Technol Res Ctr AMTEC, Skudai 81310, Johor Bahru, Malaysia
[3] Univ Malaysia Pahang, Ctr Excellence Adv Res Fluid Flow CARIFF, Gambang 26300, Pahang, Malaysia
关键词
zeolite carbon composite; mixed matrix membrane; PDMS coating; P84; co-polyimide; air separation; CARBON MOLECULAR-SIEVE; TEMPLATED CARBON; COMPOSITE MEMBRANES; GAS PERMEATION; H-2; STORAGE; ZEOLITE-Y; POLYIMIDE; CO2; O-2/N-2; FILLERS;
D O I
10.3390/membranes10100267
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
This research introduces zeolite carbon composite (ZCC) as a new filler on polymeric membranes based on the BTDA-TDI/MDI (P84) co-polyimide for the air separation process. The separation performance was further improved by a polydimethylsiloxane (PDMS) coating to cover up the surface defect. The incorporation of 1 wt% ZCC into P84 co-polyimide matrix enhanced the O-2 permeability from 7.12 to 18.90 Barrer (2.65 times) and the O-2/N-2 selectivity from 4.11 to 4.92 Barrer (19.71% improvement). The PDMS coating on the membrane further improved the O-2/N-2 selectivity by up to 60%. The results showed that the incorporation of ZCC and PDMS coating onto the P84 co-polyimide membrane was able to increase the overall air separation performance.
引用
收藏
页码:1 / 14
页数:13
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