Single crystal growth from light, volatile and reactive materials using lithium and calcium flux

被引：40

作者：

Jesche, A. ^{[1
]}

Canfield, P. C. ^{[1
,2
]}

机构：

[1] Iowa State Univ, Ames Lab, Ames, IA 50011 USA

[2] Iowa State Univ, Dept Phys & Astron, Ames, IA USA

来源：

PHILOSOPHICAL MAGAZINE | 2014年 / 94卷 / 21期

关键词：

crystal growth; solution growth; nitrides; X-ray diffraction; magnetic properties; INTERMETALLIC COMPOUNDS; DICALCIUM NITRIDE; SYSTEM; TRANSITION; PHASE; Y2NI7; NI; FERROMAGNETISM; HYDRIDE; ALLOYS;

D O I：

10.1080/14786435.2014.913114

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

We present a method for the solution growth of single crystals from reactive Li and Ca melts and its application to the synthesis of several, representative compounds. Among these, single crystalline Li3N, Li-2(Li1-xTx) N with T = {Mn, Fe, Co}, LiCaN, Li2C2, LiRh and LiIr from Li-rich flux, as well as Ca2N, CaNi2, CaNi3, YbNi2, Y2Ni7 and LaNi5 from Ca-rich flux could be obtained. Special emphasize is given on the growth of nitrides using commercially available Li3N and Ca3N2 powders as the nitrogen source instead of N-2 gas.

引用

页码：2372 / 2402

页数：31

共 46 条

[1] Investigation of weak itinerant ferromagnetism and critical behavior of Y2Ni7 [J].

Bhattacharyya, A. ;

Jain, Deepti ;

Ganesan, V. ;

Giri, S. ;

Majumdar, S. .

PHYSICAL REVIEW B, 2011, 84 (18)

[2] SYNTHESIS AND STRUCTURE OF LI2PT AND LIPT [J].

BRONGER, W ;

NACKEN, B ;

PLOOG, K .

JOURNAL OF THE LESS-COMMON METALS, 1975, 43 (01) :143-146

[3] Magnetic and electronic properties of the LaNi5-xCux system [J].

Burzo, E ;

Chiuzbaian, SG ;

Chioncel, L ;

Neumann, M .

JOURNAL OF PHYSICS-CONDENSED MATTER, 2000, 12 (27) :5897-5904

[4] CALCIUM-NICKEL INTERMETALLIC COMPOUNDS [J].

BUSCHOW, KHJ .

JOURNAL OF THE LESS-COMMON METALS, 1974, 38 (01) :95-98

[5] STRUCTURE AND OCCURRENCE OF YTTERBIUM TRANSITION-METAL COMPOUNDS [J].

BUSCHOW, KHJ .

JOURNAL OF THE LESS-COMMON METALS, 1972, 26 (03) :329-&

[6] MAGNETIC-PROPERTIES OF Y2NI7 AND ITS HYDRIDE [J].

BUSCHOW, KHJ .

JOURNAL OF THE LESS-COMMON METALS, 1984, 97 (FEB) :185-190

[7] High-temperature solution growth of intermetallic single crystals and quasicrystals [J].

Canfield, PC ;

Fisher, IR .

JOURNAL OF CRYSTAL GROWTH, 2001, 225 (2-4) :155-161

[8] INORGANIC STRUCTURE TYPES WITH REVISED SPACE-GROUPS .1. [J].

CENZUAL, K ;

GELATO, LM ;

PENZO, M ;

PARTHE, E .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1991, 47 :433-439

[9]

Cordier G., 1989, Angew. Chem. Int. Ed, V101, P1689, DOI DOI 10.1002/ANGE.19891011209

[10] CRYSTAL-STRUCTURE OF IRLI, IR3LI AND LIRH3 [J].

DONKERSLOOT, HC ;

VANVUCHT, JHN .

JOURNAL OF THE LESS-COMMON METALS, 1976, 50 (02) :279-282

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