X-ray diffraction studies, electrical and optical properties of some metal complexes of the ligand including 1-amino-3-(N-benzylamino) propane

被引：16

作者：

Aydogdu, Y ^{[1
]}

Yakuphanoglu, F

Aydogdu, A

Sekerci, M

Balci, Y

Aksoy, I

机构：

[1] Firat Univ, Fac Arts & Sci, Dept Phys, Elazig, Turkey

[2] Firat Univ, Fac Arts & Sci, Dept Chem, Elazig, Turkey

[3] Inonu Univ, Fac Arts & Sci, Dept Phys, Malatya, Turkey

来源：

SYNTHETIC METALS | 1999年 / 107卷 / 03期

关键词：

complex; amine; XRD; semiconductor;

D O I：

10.1016/S0379-6779(99)00167-8

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Metal complexes containing Cu+2, Ni+2 and Cd+2 of the ligand including 1-amino-3-(N-benzylamino propane) named M2 - [CdL1](Cl-2), M3 - [CuL2](NO3)(2), M4 - [CuL2](Cl-2) and M5 - [NiL2](Cl-2) were investigated structurally by X-ray diffraction (XRD), electrically by two probe and optically by optical methods. From the XRD data, the unit cells of the samples were found as M2, monoclinic, and M3, M4 and M5, triclinic. Hot probe and thermoelectric power measurements indicated that the complexes M2, M3, M4 and M5 have n-type of electrical conductivity and optical band gaps of the complexes are 1.66, 1.31, 1.25 and 1.29 eV, respectively. (C) 1999 Elsevier Science S,A. All rights reserved.

引用

页码：191 / 196

页数：6

共 16 条

[11]

SHRIVER DF, 1996, INORGANIC CHEM

[12] X-RAY-DIFFRACTION STUDIES ON MOLECULAR SEMICONDUCTORS BASED ON CHARGE-TRANSFER COMPLEXES OF SUBSTITUTED PHENOTHIAZINES WITH 2,3-DICHLORO-5,6-DICYANO-P-BENZOQUINONE [J].