Synthesis of chiral coordination polymers by spontaneous resolution

被引:67
|
作者
Li, Feng
Li, Taohai
Li, Xiaoju
Li, Xing
Wang, Yuling
Cao, Rong [1 ]
机构
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
关键词
D O I
10.1021/cg0600905
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Three complexes have been synthesized from the reactions of 3,3-tetramethyleneglutaric acid (H(2)TMG), Cd(NO3)(2), and secondary ligands: [Cd(TMG)](n) (1), {[Cd(TMG)(1,10-phen), H2O] center dot 2H(2)O}(n) ( 2), and [Cd(TMG)(4,4'-bipy)](n) ( 3) ( phen = 1,10-phenanthroline, 4,4'- bipy = 4,4'-bipyridine). By adopting potential chiral ligands, metal-organic helical chains as a transmitter for chiral information, and coordination bonds as chiral discriminative interactions, the chiral coordination polymer 3 with an interesting three-dimensional architecture has been synthesized successfully by spontaneous resolution.
引用
收藏
页码:1458 / 1462
页数:5
相关论文
共 50 条
  • [31] Spontaneous resolution of chiral cobalt(III) complexes
    Kostyanovsky, RG
    Torbeev, VY
    Lyssenko, KA
    TETRAHEDRON-ASYMMETRY, 2001, 12 (19) : 2721 - 2726
  • [32] Spontaneous Resolution and Carbonation of Chiral Benzyllithium Complexes
    Lennartson, Anders
    Sundberg, Jonas
    Wiklund, Tove
    Hilmersson, Goran
    Hakansson, Mikael
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2010, (19) : 3029 - 3039
  • [33] Chiral Recognition and Resolution Based on Helical Polymers
    Hui Zou
    Qi-Liang Wu
    Li Zhou
    Xiao-Hua Hou
    Na Liu
    Zong-Quan Wu
    Chinese Journal of Polymer Science, 2021, 39 (12) : 1521 - 1527
  • [34] RESOLUTION OF ENANTIOMERS BY HPLC ON CHIRAL POLYMERS.
    Okamoto, Yoshio
    Reactive polymers. Ion exchangers, sorbents, 1987, 6 (2-3): : 339 - 340
  • [35] Chiral Recognition and Resolution Based on Helical Polymers
    Zou, Hui
    Wu, Qi-Liang
    Zhou, Li
    Hou, Xiao-Hua
    Liu, Na
    Wu, Zong-Quan
    CHINESE JOURNAL OF POLYMER SCIENCE, 2021, 39 (12) : 1521 - 1527
  • [36] Chiral Recognition and Resolution Based on Helical Polymers
    Hui Zou
    Qi-Liang Wu
    Li Zhou
    Xiao-Hua Hou
    Na Liu
    Zong-Quan Wu
    Chinese Journal of Polymer Science, 2021, 39 : 1521 - 1527
  • [37] SYNTHESIS OF CHIRAL POLYMERS HAVING CAMPHANEDIOL MOIETIES AND THEIR APPLICATIONS ON THE OPTICAL RESOLUTION OF SOME RACEMATES
    LIU, JH
    TSAI, FR
    LAI, YC
    JOURNAL OF APPLIED POLYMER SCIENCE, 1995, 58 (10) : 1713 - 1720
  • [38] SYNTHESIS OF THE NOVEL CHIRAL POLYMERS WITH MULTIDENTATE LIGAND AND RESOLUTION OF DL-AMINO ACIDS
    金仁华
    何炳林
    Science in China,SerB., 1989, Ser.B.1989 (06) : 650 - 660
  • [39] Synthesis of chiral polymers having camphanediol moieties and their applications on the optical resolution of some racemates
    Liu, Jui-Hsiang, 1713, John Wiley & Sons Inc, New York, NY, United States (58):
  • [40] SYNTHESIS OF THE NOVEL CHIRAL POLYMERS WITH MULTIDENTATE LIGAND AND RESOLUTION OF DL-AMINO ACIDS
    JIN, RH
    HE, BL
    SCIENCE IN CHINA SERIES B-CHEMISTRY, 1989, 32 (06): : 650 - 660