A Copper Coordination Polymer Based on 3-(4-Hydroxypyridinium-1-yl) Phthalic Acid: Synthesis and Crystal Structure

被引：3

作者：

Li, Fu-An ^{[1
]}

Tian, Qiao-Feng ^{[2
]}

Yang, Wei-Chun ^{[1
]}

Bai, Su-Zhen ^{[1
]}

机构：

[1] Pingdingshan Univ, Coll Chem & Chem Engn, Pingdingshan 467000, Peoples R China

[2] Zhengzhou Univ, Sias Int Univ, Zhengzhou 450052, Peoples R China

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2016年 / 46卷 / 02期

关键词：

copper; coordination polymer; 3-(4-hydroxypyridinium-1-yl) phthalic acid; METAL-ORGANIC FRAMEWORK; BUILDING-BLOCKS; CHEMISTRY; LIGANDS; CHAINS; SERIES; MOTIF;

D O I：

10.1080/15533174.2013.872140

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A three-dimensional copper-organic coordination polymer based on 3-(4-hydroxypyridinium-1-yl) phthalic acid (H2L) and -4,4-bipyridine (bpy), [Cu(L)(bpy)(1/2)(H2O)](n) (1), has been obtained by hydrothermal synthesis and characterized by elemental analysis, the powder X-ray diffraction (PXRD), UV-vis absorption spectra, and also by single-crystal X-ray diffraction. The crystal is triclinic, space group P. The L2- anions of complex 1 as a bridging ligand connect Cu(II) ions to form one-dimensional (Cu-2(L)(2))(n) chains, which are linked to build a 2D layer by the bpy ligands. The 3D supramolecular framework of complex 1 are guided or controlled by weak directional interlayer hydrogen bond interactions.

引用

页码：268 / 273

页数：6

共 27 条

[1] Polycatenation, polythreading and polyknotting in coordination network chemistry
Carlucci, L
Ciani, G
Proserpio, DM
[J]. COORDINATION CHEMISTRY REVIEWS, 2003, 246 (1-2) : 247 - 289
[2] Concerning the relationship between structural and growth synthons in crystal nucleation: Solution and crystal chemistry of carboxylic acids as revealed through IR spectroscopy
Davey, R. J.
Dent, G.
Mughal, R. K.
Parveen, S.
[J]. CRYSTAL GROWTH & DESIGN, 2006, 6 (08) : 1788 - 1796
[3] Interpenetration in [Cd(isonicotinate)2(1,2-bis(4-pyridyl)ethane)0.5(H2O)]n, a novel octahedral polymer containing an unusual two-dimensional bilayer motif generated by self-assembly of rectangle building blocks
Fu, ZY
Wu, XT
Dai, JC
Wu, LM
Cui, CP
Hu, SM
[J]. CHEMICAL COMMUNICATIONS, 2001, (18) : 1856 - 1857
[4] Interweaving of single-helical and equal double-helical chains with the same helical axis in a 3D metal-organic framework
Guo, Huadong
Guo, Xianmin
Wang, Xiao
Li, Guanghua
Guo, Zhiyong
Su, Shengqun
Zhang, Hongjie
[J]. CRYSTENGCOMM, 2009, 11 (08): : 1509 - 1511
[5] Coordination polymers of Mn2+ and Dy3+ ions built with a bent tricarboxylate: Metamagnetic and weak anti-ferromagnetic behavior
Lama, Prem
Carolina Sanudo, E.
Bharadwaj, Parimal K.
[J]. DALTON TRANSACTIONS, 2012, 41 (10) : 2979 - 2985
[6] The unique rht-MOF platform, ideal for pinpointing the functionalization and CO2 adsorption relationship
Luebke, Ryan
Eubank, Jarrod F.
Cairns, Amy J.
Belmabkhout, Youssef
Wojtas, Lukasz
Eddaoudi, Mohamed
[J]. CHEMICAL COMMUNICATIONS, 2012, 48 (10) : 1455 - 1457
[7] Guest shape-responsive fitting of porous coordination polymer with shrinkable framework
Matsuda, R
Kitaura, R
Kitagawa, S
Kubota, Y
Kobayashi, TC
Horike, S
Takata, M
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (43) : 14063 - 14070
[8] Occurence of an Octanuclear Motif of Uranyl Isophthalate with Cation-Cation Interactions through Edge-Sharing Connection Mode
Mihalcea, Ionut
Henry, Natacha
Clavier, Nicolas
Dacheux, Nicolas
Loiseau, Thierry
[J]. INORGANIC CHEMISTRY, 2011, 50 (13) : 6243 - 6249
[9] Sextuplet phenyl embrace in a metal-organic Kagome lattice
Perry, JJ
McManus, GJ
Zaworotko, MJ
[J]. CHEMICAL COMMUNICATIONS, 2004, (22) : 2534 - 2535
[10] Chiral self-threading frameworks based on polyoxometalate building blocks comprising unprecedented tri-flexure helix
Qin, Chao
Wang, Xin-Long
Yuan, Ling
Wang, En-Bo
[J]. CRYSTAL GROWTH & DESIGN, 2008, 8 (07) : 2093 - 2095

← 1 2 3 →