A purge and trap technique to capture volatile compounds combined with comprehensive two-dimensional gas chromatography/time-of-flight mass spectrometry to investigate the effect of sulfur-fumigation on Radix Angelicae Dahuricae

被引：11

作者：

Cao, Gang ^{[1
,2
]}

Li, Qinglin ^{[3
]}

Zhang, Jida ^{[4
]}

Cai, Hao ^{[1
]}

Cai, Baochang ^{[1
,2
]}

机构：

[1] Nanjing Univ Chinese Med, Coll Pharm, Nanjing 210023, Jiangsu, Peoples R China

[2] Zhejiang Chinese Med Univ, Res Ctr Tradit Chinese Med Proc Technol, Hangzhou 310053, Zhejiang, Peoples R China

[3] Zhejiang Canc Hosp, Hangzhou 310022, Zhejiang, Peoples R China

[4] Zhejiang Chinese Med Univ, Coll Basic Med Sci, Hangzhou 310053, Zhejiang, Peoples R China

来源：

BIOMEDICAL CHROMATOGRAPHY | 2014年 / 28卷 / 09期

基金：

中国国家自然科学基金;

关键词：

dynamic headspace; sulfur-fumigation; volatiles; Radix Angelicae Dahuricae; comprehensive two-dimensional gas chromatography/time-of-flight mass spectrometry; TRADITIONAL CHINESE MEDICINE; QUALITY;

D O I：

10.1002/bmc.3146

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

Sulfur-fumigation is known to reduce volatile compounds that are the main active components in herbs used in herbal medicine. We investigated changes in chemical composition between sun-dried and sulfur-fumigated Radix Angelicae Dahuricae using a purge and trap technique to capture volatile compounds, and two-dimensional gas chromatography/time-of-flight mass spectrometry for identification. Using sun-dried Radix Angelicae Dahuricae samples as a reference, the results showed that 73 volatile compounds, including 12 sulfide compounds, were found to be present only in sulfur-fumigated samples. Furthermore, 32 volatile compounds that were found in sun-dried Radix Angelicae Dahuricae samples disappeared after sulfur-fumigation. The proposed method can be applied to accurately discriminate sulfur-fumigated Radix Angelicae Dahuricae from different commercial sources. Copyright (C) 2014 John Wiley & Sons, Ltd.

引用

页码：1167 / 1172

页数：6

共 34 条

[31] Aroma dynamic characteristics during the process of variable-temperature final firing of Congou black tea by electronic nose and comprehensive two- dimensional gas chromatography coupled to time-of-flight mass spectrometry [J].

Yang, Yanqin ;

Hua, Jinjie ;

Deng, Yuliang ;

Jiang, Yongwen ;

Qian, Michael C. ;

Wang, Jinjin ;

Li, Jia ;

Zhang, Mingming ;

Dong, Chunwang ;

Yuan, Haibo .

FOOD RESEARCH INTERNATIONAL, 2020, 137

[32] Separation and analysis of phenolic acids from Salvia miltiorrhiza and its related preparations by off-line two-dimensional hydrophilic interaction chromatography x reversed-phase liquid chromatography coupled with ion trap time-of-flight mass spectrometry [J].

Sun, Wanyang ;

Tong, Ling ;

Miao, Jingzhuo ;

Huang, Jingyi ;

Li, Dongxiang ;

Li, Yunfei ;

Xiao, Hongting ;

Sun, Henry ;

Bi, Kaishun .

JOURNAL OF CHROMATOGRAPHY A, 2016, 1431 :79-88

[33] Investigation of the effect of the drying techniques on the volatile constituents' profiles of sow thistle (Sonchus oleraceus L.) using headspace solid-phase microextraction with comprehensive two-dimensional gas chromatography-time of flight mass spectrometry (HS-SPME-GC x GC-ToFMS) [J].

Mahmoud, Engy ;

Jelen, Henryk ;

Ali, Hatem ;

Farouk, Amr .

EUROPEAN FOOD RESEARCH AND TECHNOLOGY, 2025,

[34] Solid phase microextraction coupled with comprehensive two-dimensional gas chromatography-time-of-flight mass spectrometry for high-resolution metabolite profiling in apples: Implementation of structured separations for optimization of sample preparation procedure in complex samples [J].

Risticevic, Sanja ;

DeEll, Jennifer R. ;

Pawliszyn, Janusz .

JOURNAL OF CHROMATOGRAPHY A, 2012, 1251 :208-218

← 1 2 3 4 →