A purge and trap technique to capture volatile compounds combined with comprehensive two-dimensional gas chromatography/time-of-flight mass spectrometry to investigate the effect of sulfur-fumigation on Radix Angelicae Dahuricae

被引：11

作者：

Cao, Gang ^{[1
,2
]}

Li, Qinglin ^{[3
]}

Zhang, Jida ^{[4
]}

Cai, Hao ^{[1
]}

Cai, Baochang ^{[1
,2
]}

机构：

[1] Nanjing Univ Chinese Med, Coll Pharm, Nanjing 210023, Jiangsu, Peoples R China

[2] Zhejiang Chinese Med Univ, Res Ctr Tradit Chinese Med Proc Technol, Hangzhou 310053, Zhejiang, Peoples R China

[3] Zhejiang Canc Hosp, Hangzhou 310022, Zhejiang, Peoples R China

[4] Zhejiang Chinese Med Univ, Coll Basic Med Sci, Hangzhou 310053, Zhejiang, Peoples R China

来源：

BIOMEDICAL CHROMATOGRAPHY | 2014年 / 28卷 / 09期

基金：

中国国家自然科学基金;

关键词：

dynamic headspace; sulfur-fumigation; volatiles; Radix Angelicae Dahuricae; comprehensive two-dimensional gas chromatography/time-of-flight mass spectrometry; TRADITIONAL CHINESE MEDICINE; QUALITY;

D O I：

10.1002/bmc.3146

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

Sulfur-fumigation is known to reduce volatile compounds that are the main active components in herbs used in herbal medicine. We investigated changes in chemical composition between sun-dried and sulfur-fumigated Radix Angelicae Dahuricae using a purge and trap technique to capture volatile compounds, and two-dimensional gas chromatography/time-of-flight mass spectrometry for identification. Using sun-dried Radix Angelicae Dahuricae samples as a reference, the results showed that 73 volatile compounds, including 12 sulfide compounds, were found to be present only in sulfur-fumigated samples. Furthermore, 32 volatile compounds that were found in sun-dried Radix Angelicae Dahuricae samples disappeared after sulfur-fumigation. The proposed method can be applied to accurately discriminate sulfur-fumigated Radix Angelicae Dahuricae from different commercial sources. Copyright (C) 2014 John Wiley & Sons, Ltd.

引用

页码：1167 / 1172

页数：6

共 33 条

[21] Analysis of volatile organic compounds released from the decay of surrogate human models simulating victims of collapsed buildings by thermal desorption-comprehensive two-dimensional gas chromatography-time of flight mass spectrometry [J].

Agapiou, A. ;

Zorba, E. ;

Mikedi, K. ;

McGregor, L. ;

Spiliopoulou, C. ;

Statheropoulos, M. .

ANALYTICA CHIMICA ACTA, 2015, 883 :99-108

[22] Analysis of nitrogenous organic compounds from mainstream cigarette smoke using low-temperature solvent extraction followed by comprehensive two-dimensional gas chromatography with high-resolution time-of-flight mass spectrometry [J].

Xiang, Zhangmin ;

Cai, Kai ;

Zhou, Shuping ;

Geng, Zhaoliang ;

Pan, Wenjie .

JOURNAL OF SEPARATION SCIENCE, 2015, 38 (15) :2655-2663

[23] Analysis of Volatiles in Laobaigan Base Baijiu Manufactured by Traditional Technology and Mechanized Technology Using Comprehensive Two-Dimensional Gas Chromatography / Time of Flight Mass Spectrometry [J].

Ma Y. ;

Zheng F. ;

Huang M. ;

Zhang Y. ;

Zhang F. ;

Sun B. .

Journal of Chinese Institute of Food Science and Technology, 2019, 19 (03) :266-280

[24] Analytical method of free and conjugated neutral aroma components in tobacco by solvent extraction coupled with comprehensive two-dimensional gas chromatography-time-of-flight mass spectrometry [J].

Ding, Yu ;

Zhu, Lijun ;

Liu, Shaomin ;

Yu, Hanqing ;

Dai, Ya .

JOURNAL OF CHROMATOGRAPHY A, 2013, 1280 :122-127

[25] Aroma Identification and Traceability of the Core Sub-Producing Area in the Helan Mountain Eastern Foothills Using Two-Dimensional Gas Chromatography and Time-of-Flight Mass Spectrometry and Chemometrics [J].

Zhang, Yuanke ;

Cui, Zefang ;

Li, Jianing ;

Wei, Mengyuan ;

Wang, Yue ;

Jiang, Wenguang ;

Fang, Yulin ;

Sun, Xiangyu ;

Ge, Qian .

FOODS, 2024, 13 (22)

[26] Comprehensive two-dimensional gas chromatography-time of flight mass spectrometry as a tool for tracking roasting-induced changes in the volatilome of cold-pressed rapeseed oil [J].

Drabinska, Natalia ;

Siger, Aleksander ;

Jelen, Henryk .

ANALYTICAL AND BIOANALYTICAL CHEMISTRY, 2023, 415 (13) :2523-2534

[27] Characterization of the key differential volatile components in different grades of Dianhong Congou tea infusions by the combination of sensory evaluation, comprehensive two-dimensional gas chromatography-time-of-flight mass spectrometry, and odor activity value [J].

Chen, Jiayu ;

Yang, Yanqin ;

Deng, Yuliang ;

Liu, Zhengquan ;

Shen, Shuai ;

Zhu, Jiayi ;

Yuan, Haibo ;

Jiang, Yongwen .

LWT-FOOD SCIENCE AND TECHNOLOGY, 2022, 165

[28] Study of traditional Chinese medicine volatile oils from different geographical origins by comprehensive two-dimensional gas chromatography-time-of-flight mass spectrometry (GC x GC-TOFMS) in combination with multivariate analysis [J].

Qiu, Yaqiong ;

Lu, Xin ;

Pang, Tao ;

Zhu, Shukui ;

Kong, Hongwei ;

Xu, Guowang .

JOURNAL OF PHARMACEUTICAL AND BIOMEDICAL ANALYSIS, 2007, 43 (05) :1721-1727

[29] Exploring the Extra-Virgin Olive Oil Volatilome by Adding Extra Dimensions to Comprehensive Two-Dimensional Gas Chromatography and Time-of-Flight Mass Spectrometry Featuring Tandem Ionization: Validation of Ripening Markers in Headspace Linearity Conditions [J].

Stilo, Federico ;

Liberto, Erica ;

Reichenbach, Stephen E. ;

Tao, Qingping ;

Bicchi, Carlo ;

Cordero, Chiara .

JOURNAL OF AOAC INTERNATIONAL, 2021, 104 (02) :274-287

[30] A chemical profiling solution for Chinese medicine formulas using comprehensive and loop-based multiple heart-cutting two-dimensional liquid chromatography coupled with quadrupole time-of-flight mass spectrometry [J].

Qiao, Xue ;

Wang, Qi ;

Song, Wei ;

Qian, Yi ;

Xiao, Yao ;

An, Rong ;

Guo, De-an ;

Ye, Min .

JOURNAL OF CHROMATOGRAPHY A, 2016, 1438 :198-204

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