Cobalt-Catalyzed Cyclization of Carbon Monoxide, Imine, and Epoxide

被引：27
作者：
Zhang, Yubo [1 ]
Ji, Jiamin [1 ]
Zhang, Xiuliang [1 ]
Lin, Shaohui [1 ]
Pan, Qinmin [1 ]
Jia, Li [2 ]
机构：
[1] Soochow Univ, Green Polymer & Catalysis Technol Lab GAPCT, Jiangsu Key Lab Adv Funct Polymer Design & Applic, Key Lab Organ Synth Jiangsu Prov,Coll Chem Chem E, Suzhou 215123, Peoples R China
[2] Univ Akron, Dept Polymer Sci, Akron, OH 44325 USA
来源：
ORGANIC LETTERS | 2014年 / 16卷 / 08期
基金：
美国国家科学基金会; 中国国家自然科学基金;
关键词：
CARBONYLATIVE RING EXPANSION; POLY-BETA-PEPTOIDS; ALTERNATING COPOLYMERIZATION; PROPYLENE-OXIDE; MULTICOMPONENT SYNTHESIS; CO; ROUTE; POLYESTERS; AZIRIDINES; COMPLEXES;
D O I：
10.1021/ol500549c
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Cobalt-catalyzed cyclization of CO, imine, and epoxide has been developed. A convenient catalyst system composed of Co-2(CO)(8) and LiCl is identified, and the substrate scope has been explored. The reaction provides an efficient method for the synthesis of substituted 1,3-oxazinan-4-ones.
引用
收藏
页码：2130 / 2133
页数：4
相关论文
共 50 条
  • [41] Cobalt-Catalyzed Acceptorless Dehydrogenation of Primary Amines to Nitriles
    Tian, Haitao
    Ding, Cai-Yun
    Liao, Rong-Zhen
    Li, Man
    Tang, Conghui
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2024, 146 (17) : 11801 - 11810
  • [42] Cobalt-catalyzed asymmetric hydroboration of aryl ketones with pinacolborane
    Guo, Jun
    Chen, Jianhui
    Lu, Zhan
    CHEMICAL COMMUNICATIONS, 2015, 51 (26) : 5725 - 5727
  • [43] Iron- and Cobalt-Catalyzed Synthesis of Carbene Phosphinidenes
    Pal, Kuntal
    Hemming, Oliver B.
    Day, Benjamin M.
    Pugh, Thomas
    Evans, David J.
    Layfield, Richard A.
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2016, 55 (05) : 1690 - 1693
  • [44] Cobalt-Catalyzed Facial-Selective Hydroalkylation of Cyclopropenes
    Zhang, Zhi-Lin
    Li, Zhen
    Xu, Yuan-Tai
    Yu, Lu
    Kuang, Jian
    Li, Yan
    Wang, Jia-Wang
    Tian, Changlin
    Lu, Xi
    Fu, Yao
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2023, 62 (30)
  • [45] Cobalt-Catalyzed Regio- and Enantioselective Allylic Amination
    Ghorai, Samir
    Chirke, Sahadev Shrihari
    Xu, Wen-Bin
    Chen, Jia-Feng
    Li, Changkun
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2019, 141 (29) : 11430 - 11434
  • [46] Cobalt-catalyzed ammonia borane dehydrocoupling and transfer hydrogenation under aerobic conditions
    Pagano, Justin K.
    Stelmach, John P. W.
    Waterman, Rory
    DALTON TRANSACTIONS, 2015, 44 (27) : 12074 - 12077
  • [47] Cobalt-Catalyzed Annulation of Salicylaldehydes and Alkynes to Form Chromones and 4-Chromanones
    Yang, Junfeng
    Yoshikai, Naohiko
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2016, 55 (08) : 2870 - 2874
  • [48] Cobalt-Catalyzed (E)-β-Selective Hydrogermylation of Terminal Alkynes
    Radzhabov, Maxim R.
    Mankad, Neal P.
    ORGANIC LETTERS, 2021, 23 (08) : 3221 - 3226
  • [49] Cobalt-Catalyzed Asymmetric Alkylation of (Hetero)Arenes with Styrenes
    Qin, Tao
    Lv, Guowei
    Miao, Huanran
    Guan, Meihui
    Xu, Chunlu
    Zhang, Ge
    Xiong, Tao
    Zhang, Qian
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2022, 61 (26)
  • [50] Cobalt-Catalyzed Aerobic Oxidative Cyclization of 2-Aminophenols with Isonitriles: 2-Aminophenol Enabled O2 Activation by Cobalt(II)
    Liu, Jiaqi
    Hoover, Jessica M.
    ORGANIC LETTERS, 2019, 21 (12) : 4510 - 4514
12345