Cobalt-Catalyzed Cyclization of Carbon Monoxide, Imine, and Epoxide

被引：27

作者：

Zhang, Yubo ^{[1
]}

Ji, Jiamin ^{[1
]}

Zhang, Xiuliang ^{[1
]}

Lin, Shaohui ^{[1
]}

Pan, Qinmin ^{[1
]}

Jia, Li ^{[2
]}

机构：

[1] Soochow Univ, Green Polymer & Catalysis Technol Lab GAPCT, Jiangsu Key Lab Adv Funct Polymer Design & Applic, Key Lab Organ Synth Jiangsu Prov,Coll Chem Chem E, Suzhou 215123, Peoples R China

[2] Univ Akron, Dept Polymer Sci, Akron, OH 44325 USA

来源：

ORGANIC LETTERS | 2014年 / 16卷 / 08期

基金：

美国国家科学基金会; 中国国家自然科学基金;

关键词：

CARBONYLATIVE RING EXPANSION; POLY-BETA-PEPTOIDS; ALTERNATING COPOLYMERIZATION; PROPYLENE-OXIDE; MULTICOMPONENT SYNTHESIS; CO; ROUTE; POLYESTERS; AZIRIDINES; COMPLEXES;

D O I：

10.1021/ol500549c

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Cobalt-catalyzed cyclization of CO, imine, and epoxide has been developed. A convenient catalyst system composed of Co-2(CO)(8) and LiCl is identified, and the substrate scope has been explored. The reaction provides an efficient method for the synthesis of substituted 1,3-oxazinan-4-ones.

引用

页码：2130 / 2133

页数：4

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