Cobalt-Catalyzed Cyclization of Carbon Monoxide, Imine, and Epoxide

被引：27
作者：
Zhang, Yubo [1 ]
Ji, Jiamin [1 ]
Zhang, Xiuliang [1 ]
Lin, Shaohui [1 ]
Pan, Qinmin [1 ]
Jia, Li [2 ]
机构：
[1] Soochow Univ, Green Polymer & Catalysis Technol Lab GAPCT, Jiangsu Key Lab Adv Funct Polymer Design & Applic, Key Lab Organ Synth Jiangsu Prov,Coll Chem Chem E, Suzhou 215123, Peoples R China
[2] Univ Akron, Dept Polymer Sci, Akron, OH 44325 USA
来源：
ORGANIC LETTERS | 2014年 / 16卷 / 08期
基金：
美国国家科学基金会; 中国国家自然科学基金;
关键词：
CARBONYLATIVE RING EXPANSION; POLY-BETA-PEPTOIDS; ALTERNATING COPOLYMERIZATION; PROPYLENE-OXIDE; MULTICOMPONENT SYNTHESIS; CO; ROUTE; POLYESTERS; AZIRIDINES; COMPLEXES;
D O I：
10.1021/ol500549c
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Cobalt-catalyzed cyclization of CO, imine, and epoxide has been developed. A convenient catalyst system composed of Co-2(CO)(8) and LiCl is identified, and the substrate scope has been explored. The reaction provides an efficient method for the synthesis of substituted 1,3-oxazinan-4-ones.
引用
收藏
页码：2130 / 2133
页数：4
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