Preparation and Properties of Aqueous SCNTs Dispersion based on A UV-curable Polymeric Dispersant

被引：1
作者：
Yuan Yan [1 ]
Wu Haiqiang [1 ]
Liu Jingcheng [1 ]
Luo Jing [1 ]
Liu Ren [1 ]
Liu Xiaoya [1 ]
机构：
[1] Jiangnan Univ, Sch Chem & Mat Engn, Minist Educ, Key Lab Synthest & Biol Colloids, Wuxi 214122, Peoples R China
来源：
JOURNAL OF WUHAN UNIVERSITY OF TECHNOLOGY-MATERIALS SCIENCE EDITION | 2018年 / 33卷 / 02期
基金：
中国国家自然科学基金;
关键词：
single-walled carbon nanotubes (SCNTs); polymeric dispersant; UV-curable; conductive; water resistance; WALLED CARBON NANOTUBES; SINGLE-WALL; SOLUBILIZATION; WATER; SURFACTANTS; ADSORPTION; COATINGS; FILMS;
D O I：
10.1007/s11595-018-1849-0
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
A novel photosensitive copolymer P(SS-co-AA-g-GMA) (PSAG) was synthesized and utilized to noncovalently functionalize pristine single-walled carbon nanotubes (SCNTs). PSAG was highly effective for the solubilization of SCNTs in water and validated by UV-vis absorption spectra experiments, resulting in homogeneous and stable PSAG-SCNT aqueous dispersion. The microstructure of SCNTs was observed through Raman spectroscopy and transmission electron microscopy. In addition, compared with the two common polymeric dispersants of Triton X-100 and PSS, PSAG demonstrated more effective performances for dispersing SCNTs under identical conditions. Furthermore, the photosensitive PSAG-SCNTs can be crosslinked after UV irradiation, leading to significant improvement in the water resistance of SCNT films. UV-cured films can be transferred to plastic wrap to form a flexible film with high electrical conductivity.
引用
收藏
页码：485 / 491
页数：7
相关论文
共 34 条
  • [1] Adsorption of Triton X-series surfactants and its role in stabilizing multi-walled carbon nanotube suspensions
    Bai, Yingchen
    Lin, Daohui
    Wu, Fengchang
    Wang, Zhenyu
    Xing, Baoshan
    [J]. CHEMOSPHERE, 2010, 79 (04) : 362 - 367
  • [2] Carbon nanotubes - the route toward applications
    Baughman, RH
    Zakhidov, AA
    de Heer, WA
    [J]. SCIENCE, 2002, 297 (5582) : 787 - 792
  • [3] Noncovalent engineering of carbon nanotube surfaces by rigid, functional conjugated polymers
    Chen, J
    Liu, HY
    Weimer, WA
    Halls, MD
    Waldeck, DH
    Walker, GC
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (31) : 9034 - 9035
  • [4] Humidity sensors fabricated with photo-curable electrolyte inks using an ink-jet printing technique and their properties
    Cho, Nam-Bu
    Lim, Tai-Ho
    Jeon, Young-Min
    Gong, Myoung-Seon
    [J]. SENSORS AND ACTUATORS B-CHEMICAL, 2008, 130 (02) : 594 - 598
  • [5] THE CHEMISTRY AND APPLICATIONS OF UV-CURED ADHESIVES
    HADDON, MR
    SMITH, TJ
    [J]. INTERNATIONAL JOURNAL OF ADHESION AND ADHESIVES, 1991, 11 (03) : 183 - 186
  • [6] HELICAL MICROTUBULES OF GRAPHITIC CARBON
    IIJIMA, S
    [J]. NATURE, 1991, 354 (6348) : 56 - 58
  • [7] Production of aqueous colloidal dispersions of carbon nanotubes
    Jiang, LQ
    Gao, L
    Sun, J
    [J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2003, 260 (01) : 89 - 94
  • [8] Solubilization of single-wall carbon nanotubes by supramolecular encapsulation of helical amylose
    Kim, OK
    Je, JT
    Baldwin, JW
    Kooi, S
    Pehrsson, PE
    Buckley, LJ
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (15) : 4426 - 4427
  • [9] Study of the effect of modified and pristine carbon nanotubes on the properties of poly(vinyl alcohol) nanocomposite films
    Konidari, M. V.
    Soulas, D. N.
    Papadokostaki, K. G.
    Sanopoulou, M.
    [J]. JOURNAL OF APPLIED POLYMER SCIENCE, 2012, 125 : E471 - E477
  • [10] Influence of chain transfer agent on the cross-linking of poly(n-butyl methaerylate-co-N-methylol acrylamide) latex particles and films
    Krishnan, S
    Klein, A
    El-Aasser, MS
    Sudol, ED
    [J]. MACROMOLECULES, 2003, 36 (10) : 3511 - 3518
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