Effect of hot-wire passivation on the properties of hydrogenated microcrystalline silicon films to reduce post-deposition oxidation

被引:2
作者
Mitsuhashi, S. [1 ]
Tabata, A. [1 ]
Mizutani, T. [1 ]
机构
[1] Nagoya Univ, Dept Elect Engn & Comp Sci, Chikusa Ku, Nagoya, Aichi 4648603, Japan
关键词
silicon; oxidation reduction; chemical vapor deposition; microcrystallinity; FT-IR measurements;
D O I
10.1016/j.jnoncrysol.2006.04.020
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Hydrogenated microcrystalline silicon (mu c-Si:H) films have a large number of grain boundaries that oxidize after deposition, leading to deterioration of device performance. In this study, post-treatment of pc-Si:H thin films was carried out with methane-related radicals generated by a hot wire. The effect of the hot-wire passivation on the properties of the mu c-Si:H thin films was investigated using Fourier-transform infrared (FT-IR) transmission spectroscopy. Through post-treatment, hydrogen on the silicon-crystallite surface was substituted with hydrocarbon. Further, an increase in filament temperature (T-ft) was found to enhance passivation. For films treated at T-ft above 1700 degrees C, post-oxidation and nitridation hardly occurred, whereas films treated at T-ft below 1400 degrees C were oxidized and nitrided even after post-treatment. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:2943 / 2946
页数:4
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