Hydrogen storage in the giant-pore metal-organic frameworks MIL-100 and MIL-101

被引：728

作者：

Latroche, Michel ^{[1
]}

Surble, Suzy

Serre, Christian

Mellot-Draznieks, Caroline

Llewellyn, Philip L.

Lee, Jin-Ho

Chang, Jong-San

Jhung, Sung Hwa

Ferey, Gerard

机构：

[1] CNRS, Lab Chim Met Terres Rares, UPR 209, F-94320 Thiais, France

[2] Univ Versailles, UMR 8180, Inst Lavoisier, F-78035 Versailles, France

[3] Univ Aix Marseille 1, CNRS, UMR 6121, Ctr St Jerome, F-13397 Marseille 20, France

[4] Korea Res Inst Chem Technol, Taejon 305600, South Korea

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 48期

关键词：

carboxylate ligands; chromium; hydrogen; mesoporous materials; physisorption;

D O I：

10.1002/anie.200600105

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Large hydrogen-storage capacity at liquid-nitrogen temperature is exhibited by the metal-organic framework MIL-101. In the zeotype architecture of this porous solid (see picture) each intersection of the cages is occupied by a supertetrahedron formed by trimers of chromium octahedra assembled with benzene-1,4-dicarboxylate ligands. (Figure Presented). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：8227 / 8231

页数：5

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