Evaluation of a pilot-scale sewage biogas powered 2.8 kWe Solid Oxide Fuel Cell: Assessment of heat-to-power ratio and influence of oxygen content

被引:27
作者
de Arespacochaga, N. [1 ]
Valderrama, C. [2 ]
Peregrina, C.
Mesa, C. [1 ]
Bouchy, L. [3 ]
Cortina, J. L. [1 ]
机构
[1] Water Technol Ctr CETaqua, Barcelona 08940, Spain
[2] Univ Politecn Catalunya Barcelona Tech, Dept Chem Engn, Barcelona, Spain
[3] Aqual UK, Bristol, Avon, England
关键词
Biogas; Solid Oxide Fuel Cell; Gas reforming; Biogas treatment; Heat-to-power ratio; Energy valorisation; PERFORMANCE EVALUATION; ECONOMIC-ANALYSIS; HYDROGEN-SULFIDE; LANDFILL GAS; OPERATION; ENERGY; BIOMASS; OXIDATION; SYSTEMS; WASTE;
D O I
10.1016/j.jpowsour.2015.09.086
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Biogas from anaerobic digestion of organic matter is a promising renewable energy source and fuel cells appear as a breakthrough technology to improve the performance of the biogas-to-energy valorisation chain. The vast majority of studies addressing biogas energy recovery through Solid Oxide Fuel Cells published in recent years correspond to simulations and lab-scale performance with synthetic biogas. This paper assesses the pilot performance of a 2.8 kW(e) SOFC unit powered with cleaned sewage biogas for around 700 h in a Wastewater Treatment Plant. The biogas thorough treatment consisting of a biological desulphurisation with a biotrickling filter followed by a deep cleaning step based on adsorption is successful for removing sulphur compounds, siloxanes and hydrocarbons. The influence of the heat-to-power ratio on fuel cell performance is investigated operating the system at O/C ratio of 2, reforming temperature of 550 degrees C, stack temperature of 800 degrees C and at a constant voltage of 43 V. At optimized conditions for electrical production satisfying heat demand in the WWTP, system electrical and thermal efficiencies account for 34% and 28%. Cogeneration efficiency remains constant at around 59-62% for all the heat-to-power ratios tested. Furthermore, the impact of the oxygen content in the biogas is also studied. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码:325 / 335
页数:11
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