Microemulsion synthesis of fluorinated latex spheres

被引:16
作者
Sacanna, S [1 ]
Koenderink, GH [1 ]
Philipse, AP [1 ]
机构
[1] Univ Utrecht, Debye Inst, Vant Hoff Lab Phys & Colloid Chem, NL-3584 CH Utrecht, Netherlands
关键词
D O I
10.1021/la049811x
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The polymerization in a microemulsion, which provides a useful technique for the synthesis of very small fluorinated latex particles in the size range 17-50 nm, was described. The microemulsion was irradiated at room temperature for 8 h by an 8-W ultraviolet (UV) lightbulb to promote the radical polymerization. Dynamic light scattering (DLS) and transmission electron microscopy (TEM) showed that the resulting particles were monodisperse and spherical. It was concluded that the colloidal system is useful as a well-defined optically transparent host suspension for diffusion studies on tracer particles by light scattering experiments.
引用
收藏
页码:8398 / 8400
页数:3
相关论文
共 7 条
[1]   THEORY OF KINETICS OF MICELLAR EQUILIBRIA AND QUANTITATIVE INTERPRETATION OF CHEMICAL RELAXATION STUDIES OF MICELLAR SOLUTIONS OF IONIC SURFACTANTS [J].
ANIANSSON, EAG ;
WALL, SN ;
ALMGREN, M ;
HOFFMANN, H ;
KIELMANN, I ;
ULBRICHT, W ;
ZANA, R ;
LANG, J ;
TONDRE, C .
JOURNAL OF PHYSICAL CHEMISTRY, 1976, 80 (09) :905-922
[2]   Microemulsion polymerization of styrene in the presence of a cationic emulsifier [J].
Capek, I .
ADVANCES IN COLLOID AND INTERFACE SCIENCE, 2001, 92 (1-3) :195-233
[3]   MICROEMULSION POLYMERIZATION OF STYRENE [J].
GUO, JS ;
ELAASSER, MS ;
VANDERHOFF, JW .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1989, 27 (02) :691-710
[4]   Preparation and properties of optically transparent aqueous dispersions of monodisperse fluorinated colloids [J].
Koenderink, GH ;
Sacanna, S ;
Pathmamanoharan, C ;
Rasa, M ;
Philipse, AP .
LANGMUIR, 2001, 17 (20) :6086-6093
[5]   Effect of photoirradiation on potassium persulfate-surface oxidation of low-density polyethylene film [J].
Kubota, H ;
Hariya, Y ;
Kuroda, S ;
Kondo, T .
POLYMER DEGRADATION AND STABILITY, 2001, 72 (02) :223-227
[6]  
Livingston J, 1927, J AM CHEM SOC, V49, P338
[7]   Atomic force microscopy and magnetic force microscopy study of model colloids [J].
Rasa, M ;
Kuipers, BWM ;
Philipse, AP .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2002, 250 (02) :303-315