Influence of N interstitials on the electronic properties of GaAsN alloys

被引:26
作者
Jin, Y. [1 ,2 ]
Jock, R. M. [1 ,2 ]
Cheng, H. [2 ]
He, Y. [3 ]
Mintarov, A. M. [3 ]
Wang, Y. [4 ]
Kurdak, C. [2 ]
Merz, J. L. [3 ]
Goldman, R. S. [1 ,2 ]
机构
[1] Univ Michigan, Dept Mat Sci & Engn, Ann Arbor, MI 48109 USA
[2] Univ Michigan, Dept Phys, Ann Arbor, MI 48109 USA
[3] Univ Notre Dame, Dept Elect Engn, Notre Dame, IN 46556 USA
[4] Los Alamos Natl Lab, Los Alamos, NM 87545 USA
基金
美国国家科学基金会;
关键词
carrier density; carrier mobility; conduction bands; gallium arsenide; gallium compounds; III-V semiconductors; impurity states; interstitials; nuclear chemical analysis; Raman spectra; rapid thermal annealing; semiconductor thin films; wide band gap semiconductors; NITROGEN INCORPORATION; GA(AS; N); LAYERS; TEMPERATURE;
D O I
10.1063/1.3187915
中图分类号
O59 [应用物理学];
学科分类号
摘要
We have used rapid thermal annealing to investigate the influence of N interstitials on the electronic properties of GaAsN alloys. Nuclear reaction analysis reveals an annealing-induced decrease in the interstitial N concentration, while the total N composition remains constant. Corresponding signatures for the reduced interstitial N concentration are apparent in Raman spectra. Following annealing, both the room-T carrier concentration, n, and the mobility increase. At higher measurement-Ts, a thermally activated increase in n suggests the presence of a trap near GaAsN conduction band edge with activation energy 85 +/- 15 meV. The annealing-induced increase in n suggests the association of the trap with interstitial N.
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页数:3
相关论文
共 19 条
[1]   Concentration of interstitial and substitutional nitrogen in GaNxAs1-x [J].
Ahlgren, T ;
Vainonen-Ahlgren, E ;
Likonen, J ;
Li, W ;
Pessa, M .
APPLIED PHYSICS LETTERS, 2002, 80 (13) :2314-2316
[2]   Organometallic vapor phase epitaxy of GaAs1-xNx alloy layers on GaAs(001):: Nitrogen incorporation and lattice parameter variation [J].
Beaudry, JN ;
Masut, RA ;
Desjardins, P ;
Wei, R ;
Chicoine, M ;
Bentoumi, G ;
Leonelli, R ;
Schiettekatte, F ;
Guillon, S .
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A, 2004, 22 (03) :771-775
[3]   1.3 μm GaInAsN laserdiodes with improved high temperature performance [J].
Fischer, M ;
Gollub, D ;
Forchel, A .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS BRIEF COMMUNICATIONS & REVIEW PAPERS, 2002, 41 (2B) :1162-1163
[4]   III-N-V semiconductors for solar photovoltaic applications [J].
Geisz, JF ;
Friedman, DJ .
SEMICONDUCTOR SCIENCE AND TECHNOLOGY, 2002, 17 (08) :769-777
[5]   GaInNAs long-wavelength lasers: progress and challenges [J].
Harris, JS .
SEMICONDUCTOR SCIENCE AND TECHNOLOGY, 2002, 17 (08) :880-891
[6]  
JIN Y, APPL PHYS L IN PRESS, P23124
[7]   Nitrogen-related electron traps in Ga(As,N) layers (≤3% N) [J].
Krispin, P ;
Gambin, V ;
Harris, JS ;
Ploog, KH .
JOURNAL OF APPLIED PHYSICS, 2003, 93 (10) :6095-6099
[8]   InGaAsN solar cells with 1.0 eV band gap, lattice matched to GaAs [J].
Kurtz, SR ;
Allerman, AA ;
Jones, ED ;
Gee, JM ;
Banas, JJ ;
Hammons, BE .
APPLIED PHYSICS LETTERS, 1999, 74 (05) :729-731
[9]   Nitrogen-dependent optimum annealing temperature of Ga(As,N) [J].
Mussler, G ;
Chauveau, JM ;
Trampert, A ;
Ramsteiner, M ;
Däweritz, L ;
Ploog, KH .
JOURNAL OF CRYSTAL GROWTH, 2004, 267 (1-2) :60-66
[10]   Nonradiative recombination centers in Ga(As,N) and their annealing behavior studied by Raman spectroscopy [J].
Ramsteiner, M ;
Jiang, DS ;
Harris, JS ;
Ploog, KH .
APPLIED PHYSICS LETTERS, 2004, 84 (11) :1859-1861