BISMUTH PHOSPHINATES: TEMPERATURE-DEPENDENT FORMATION OF A MACROCYCLE AND 1D COORDINATION POLYMER

被引：10

作者：

Metre, Ramesh K. ^{[1
]}

Kundu, Subrata ^{[1
]}

Narayanan, R. Suriya ^{[2
]}

Chandrasekhar, Vadapalli ^{[1
,2
]}

机构：

[1] Indian Inst Technol, Dept Chem, Kanpur 208016, Uttar Pradesh, India

[2] Natl Inst Sci Educ & Res, Sch Chem Sci, Bhubaneswar 751005, Odisha, India

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2015年 / 190卷 / 12期

关键词：

Bismuth; phosphinates; coordination polymer; STRUCTURAL-CHARACTERIZATION; CHEMISTRY;

D O I：

10.1080/10426507.2015.1072192

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of Ph3Bi with a sterically hindered phosphinic acid, 1,1,2,3,3-pentamethyltrimethylene phosphinic acid, {cycP(O)OH2H(2)O}, at two different temperatures, one at refluxing conditions and another at room temperature, in tetrahydrofuran has been investigated. At refluxing conditions, cleavage of two Bi-C bonds (of BiPh3) leads to the formation of a 16-member macrocycle [(PhBi)(4)(cycPO(2))(8)] (1). On the other hand, the reaction at room temperature leads to the cleavage of one Bi-C bond only, affording a 1D polymer [(Ph2Bi)(cycPO(2))](n), ((1,1,2,3,3-pentamethyltrimethylene phosphinate is denoted as cycPO(2)) (2). Both the complexes were characterized by single crystal X-ray diffraction. In both complexes the phosphinate ligands are present in an anisobidentate (bridging) coordination mode.

引用

页码：2134 / 2141

页数：8

共 25 条

[1] Remarkable in vitro bactericidal activity of bismuth(III) sulfonates against Helicobacter pylori [J].

Andrews, Philip C. ;

Busse, Madleen ;

Deacon, Glen B. ;

Ferrero, Richard L. ;

Junk, Peter C. ;

MacLellan, Jonathan G. ;

Vom, Amelia .

DALTON TRANSACTIONS, 2012, 41 (38) :11798-11806

[2] Studies on bismuth carboxylates-synthesis and characterization of a new structural form of bismuth(III) dipicolinate [J].

Anjaneyulu, O. ;

Swamy, K. C. Kumara .

JOURNAL OF CHEMICAL SCIENCES, 2011, 123 (02) :131-137

[3] A new class of eight-membered Sn2P2O4 heterocycles.: Crystal structure and electrolytic dissociation in solution of cyclo-[R2Sn(OPPh2O)2SnR2(O3SCF3)2 (R = Me, t-Bu) [J].

Beckmann, J ;

Dakternieks, D ;

Duthie, A ;

Mitchell, C .

ORGANOMETALLICS, 2003, 22 (10) :2161-2164

[4]

Brandenburg K., 2005, DIAMOND VERSION 3 1E

[5] Bismuth compounds and preparations with biological or medicinal relevance [J].

Briand, GG ;

Burford, N .

CHEMICAL REVIEWS, 1999, 99 (09) :2601-2657

[6] Bi38 Oxocarboxylate Cages are Keplerates - Synthesis and Structural Characterization of Two Bi38 Oxocarboxylate Cages [J].

Chandrasekhar, Vadapalli ;

Metre, Ramesh K. ;

Sahoo, Dipankar .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2014, 2014 (01) :164-171

[7] Lipophilic bismuth phosphates: a molecular tetradecanuclear cage and a 1D-coordination polymer. Synthesis, structure and conversion to BiPO4 [J].

Chandrasekhar, Vadapalli ;

Metre, Ramesh K. ;

Narayanan, Ramakirushnan Suriya .

DALTON TRANSACTIONS, 2013, 42 (24) :8709-8716

[8] A hexaicosametallic copper(II) phosphonate [J].

Chandrasekhar, Vadapalli ;

Sahoo, Dipankar ;

Narayanan, Ramakirushnan Suriya ;

Butcher, Raymond J. ;

Lloret, Franscesc ;

Pardo, Emilio .

DALTON TRANSACTIONS, 2013, 42 (23) :8192-8196

[9] Bismuth-ferrocene carboxylates: synthesis and structure [J].

Chandrasekhar, Vadapalli ;

Metre, Ramesh K. .

DALTON TRANSACTIONS, 2012, 41 (38) :11684-11691

[10] SYNTHESIS, PROPERTIES, AND STRUCTURAL CHARACTERIZATION OF LEAD(II) BIS(DIPHENYLPHOSPHINATE), PB[OP(C6H5)2O]2 [J].

COLAMARINO, P ;

ORIOLI, PL ;

BENZINGER, WD ;

GILLMAN, HD .

INORGANIC CHEMISTRY, 1976, 15 (04) :800-804

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