A metal-organic coordination polymer based on 1,2-bis(diphenylphosphino)ethane dioxide: Synthesis, crystal structure and fluorescence of [ZnI2{Ph2P(O)-CH2CH2-P(O)Ph2}]n

被引:11
|
作者
Liu, Xiaoqing [1 ,2 ]
Yang, Xiao-Juan [1 ]
Yang, Peiju [1 ]
Liu, Yanyan [1 ]
Wu, Biao [1 ]
机构
[1] Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
关键词
Coordination polymer; Crystal structure; Zinc(II); 1,2-Bis(diphenylphosphino)ethane dioxide; COMPLEXES; OXIDES; LIGANDS; PHOSPHINE; NITRATES; ADDUCTS; OXYGEN;
D O I
10.1016/j.inoche.2009.03.019
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A zinc coordination polymer, [ZnI2{Ph2P(O)-CH2CH2-P(O)Ph-2}](n) (1), has been prepared, which features a one-dimensional concavo-convex chain with alternative ZnI2 and 1,2-bis(diphenylphosphino)ethane dioxide (dppeO(2)) moieties. The dppeO(2) ligand adopts the bridging coordination mode between two zinc atoms. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:481 / 483
页数:3
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