Hydrophobic pillared square grids for selective removal of CO2 from simulated flue gas

被引：105

作者：

Elsaidi, Sameh K. ^{[1
,2
]}

Mohamed, Mona H. ^{[1
,3
]}

Schaef, Herbert T. ^{[2
]}

Kumar, Amrit ^{[4
]}

Lusi, Matteo ^{[4
]}

Pham, Tony ^{[3
]}

Forrest, Katherine A. ^{[3
]}

Space, Brian ^{[3
]}

Xu, Wenqian ^{[5
]}

Halder, Gregory J. ^{[5
]}

Liu, Jun ^{[2
]}

Zaworotko, Michael J. ^{[3
]}

Thallapally, Praveen K. ^{[2
]}

机构：

[1] Univ Alexandria, Fac Sci, Dept Chem, Alexandria 21321, Egypt

[2] Pacific NW Natl Lab, Fundamental & Computat Sci Directorate, Richland, WA 99352 USA

[3] Univ S Florida, Dept Chem, Tampa, FL 33620 USA

[4] Univ Limerick, Dept Chem & Environm Sci, Limerick, Ireland

[5] Argonne Natl Lab, Xray Sci Div, Adv Photon Source, Argonne, IL 60439 USA

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 85期

基金：

美国国家科学基金会;

关键词：

METAL-ORGANIC FRAMEWORKS; CARBON-DIOXIDE CAPTURE; POROUS MATERIALS; AQUEOUS AMMONIA; FUEL-CELLS; ADSORPTION; SEPARATION; STORAGE; DESIGN; BINDING;

D O I：

10.1039/c5cc06577a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Capture of CO2 from flue gas is considered to be a feasible approach to mitigate the effects of anthropogenic emission of CO2. Herein we report that an isostructural family of metal organic materials (MOMs) of general formula [M(linker)(2)(pillar)], linker = pyrazine, pillar = hexaflourosilicate and M = Zn, Cu, Ni and Co exhibits highly selective removal of CO2 fromdry and wet simulated flue gas. Two members of the family, M = Ni and Co, SIFSIX-3-Ni and SIFSIX-3-Co, respectively, are reported for the first time and compared with the previously reported Zn and Cu analogs.

引用

页码：15530 / 15533

页数：4

共 33 条

[1] Membrane Gas Separation: A Review/State of the Art [J].

Bernardo, P. ;

Drioli, E. ;

Golemme, G. .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2009, 48 (10) :4638-4663

[2] Membrane technologies for CO2 separation [J].

Brunetti, A. ;

Scura, F. ;

Barbieri, G. ;

Drioli, E. .

JOURNAL OF MEMBRANE SCIENCE, 2010, 359 (1-2) :115-125

[3] Square Grid and Pillared Square Grid Coordination Polymers - Fertile Ground for Crystal Engineering of Structure and Function [J].

Burd, Stephen D. ;

Nugent, Patrick S. ;

Mohamed, Mona H. ;

Elsaidi, Sameh K. ;

Zaworotko, Michael J. .

CHIMIA, 2013, 67 (06) :372-378

[4] CO2 cryogenic separation from combined cycles integrated with molten carbonate fuel cells [J].

Chiesa, Paolo ;

Campanari, Stefano ;

Manzolini, Giampaolo .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2011, 36 (16) :10355-10365

[5] Strong CO2 Binding in a Water-Stable, Triazolate-Bridged Metal-Organic Framework Functionalized with Ethylenediamine [J].

Demessence, Aude ;

D'Alessandro, Deanna M. ;

Foo, Maw Lin ;

Long, Jeffrey R. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (25) :8784-+

[6] Carbon capture with molten carbonate fuel cells: Experimental tests and fuel cell performance assessment [J].

Discepoli, Gabriele ;

Cinti, Giovanni ;

Desideri, Umberto ;

Penchini, Daniele ;

Proietti, Stefania .

INTERNATIONAL JOURNAL OF GREENHOUSE GAS CONTROL, 2012, 9 :372-384

[7] Systematic design of pore size and functionality in isoreticular MOFs and their application in methane storage [J].

Eddaoudi, M ;

Kim, J ;

Rosi, N ;

Vodak, D ;

Wachter, J ;

O'Keeffe, M ;

Yaghi, OM .

SCIENCE, 2002, 295 (5554) :469-472

[8] Metal-Organic Framework Materials with Ultrahigh Surface Areas: Is the Sky the Limit? [J].

Farha, Omar K. ;

Eryazici, Ibrahim ;

Jeong, Nak Cheon ;

Hauser, Brad G. ;

Wilmer, Christopher E. ;

Sarjeant, Amy A. ;

Snurr, Randall Q. ;

Nguyen, SonBinh T. ;

Yazaydin, A. Oezguer ;

Hupp, Joseph T. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (36) :15016-15021

[9] Carbon Capture and Storage: How Green Can Black Be? [J].

Haszeldine, R. Stuart .

SCIENCE, 2009, 325 (5948) :1647-1652

[10] Unusual room temperature CO2 uptake in a fluoro-functionalized MOF: insight from Raman spectroscopy and theoretical studies [J].

Kanoo, Prakash ;

Reddy, Sandeep Kumar ;

Kumari, Gayatri ;

Haldar, Ritesh ;

Narayana, Chandrabhas ;

Balasubramanian, Sundaram ;

Maji, Tapas Kumar .

CHEMICAL COMMUNICATIONS, 2012, 48 (68) :8487-8489

← 1 2 3 4 →