Sustainable photochemistry: solvent-free singlet oxygen-photooxygenation of organic substrates embedded in porphyrin-loaded polystyrene beads

被引：58

作者：

Griesbeck, AG ^{[1
]}

Bartoschek, A ^{[1
]}

机构：

[1] Univ Cologne, Inst Organ Chem, D-50939 Cologne, Germany

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 15期

关键词：

D O I：

10.1039/b204017d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A solvent-free photooxygenation process that uses organic substrates embedded in porphyrin-loaded polystyrene beads as solid support is described and applied for ene- and [4+2]-cycloaddition reactions involving singlet oxygen ((1)Delta(g)).

引用

页码：1594 / 1595

页数：2

共 15 条

[1]

ADAM W, 1995, HDB ORGANIC PHOTOCHE, P311

[2]

Anastas P. T., 1998, GREEN CHEM THEORY PR

[3]

Bourdelande JL, 2001, HELV CHIM ACTA, V84, P3488, DOI 10.1002/1522-2675(20011114)84:11<3488::AID-HLCA3488>3.0.CO

[4]

2-7

[5]

Frimer A. A, 1985, SINGLET OXYGEN, VI-IV

[6] Photoinduced decarboxylation reactions -: Radical chemistry in water [J].

Griesbeck, AG ;

Kramer, W ;

Oelgemöller, M .

GREEN CHEMISTRY, 1999, 1 (04) :205-207

[7]

GRIESBECK AG, 1995, HDB ORGANIC PHOTOCHE, P301

[8]

Ogilby PR, 1996, ADV CHEM SER, V249, P113

[9] POLYMER-BASED SENSITIZERS FOR PHOTOOXIDATIONS .2. [J].

SCHAAP, AP ;

THAYER, AL ;

BLOSSEY, EC ;

NECKERS, DC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (13) :3741-3745

[10] COLLISIONAL DEACTIVATION OF O-2(1-DELTA-G) BY SOLVENT MOLECULES - COMPARATIVE EXPERIMENTS WITH O-16(2) AND O-18(2) [J].

SCHMIDT, R ;

AFSHARI, E .

BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1992, 96 (06) :788-794

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