Reactions and kinetics of unsaturated C2 hydrocarbon radicals

被引：109

作者：

Laufer, AH ^{[1
]}

Fahr, A ^{[1
]}

机构：

[1] Natl Inst Stand & Technol, Phys & Chem Properties Div, Gaithersburg, MD 20899 USA

来源：

CHEMICAL REVIEWS | 2004年 / 104卷 / 06期

关键词：

D O I：

10.1021/cr030039x

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reactions of the C2 unsaturated hydrocarbon radicals represent an important field of work that is relevant to macroscopic reaction media, such as combustion and environmental processes. The reaction kinetics and mechanisms of product formation of C2 unsaturated hydrocarbon radicals, namely, ethynyl (C2H), vinylidene (H2C=C), and vinyl (C2H3) radicals, are reviewed. The thermochemistry as well as the production and detection of these radical species are outlined. Results of relevant computational studies are discussed, and preferred rate coefficients for the radical reactions presented.

引用

页码：2813 / 2832

页数：20

共 154 条

[91] Ab initio and RRKM calculations for multichannel rate constants of the C2H3+O-2 reaction [J].

Mebel, AM ;

Diau, EWG ;

Lin, MC ;

Morokuma, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (40) :9759-9771

[92] AB-INITIO MOLECULAR-ORBITAL STUDY OF POTENTIAL-ENERGY SURFACE FOR THE REACTION OF C2H3 WITH H-2 AND RELATED REACTIONS [J].

MEBEL, AM ;

MOROKUMA, K ;

LIN, MC .

JOURNAL OF CHEMICAL PHYSICS, 1995, 103 (09) :3440-3449

[93] KINETIC AND THERMODYNAMIC ISSUES IN THE FORMATION OF AROMATIC-COMPOUNDS IN FLAMES OF ALIPHATIC FUELS [J].

MILLER, JA ;

MELIUS, CF .

COMBUSTION AND FLAME, 1992, 91 (01) :21-39

[94] ABSOLUTE RATE-CONSTANT AND PRODUCT BRANCHING RATIOS FOR THE REACTION BETWEEN H AND C2H3 AT T=213 AND 298 K [J].

MONKS, PS ;

NESBITT, FL ;

PAYNE, WA ;

SCANLON, M ;

STIEF, LJ ;

SHALLCROSS, DE .

JOURNAL OF PHYSICAL CHEMISTRY, 1995, 99 (47) :17151-17159

[95] NEAR-ULTRAVIOLET PHOTOLYSIS OF C2H2 - A PRECISE DETERMINATION OF D-0(HCC-H) [J].

MORDAUNT, DH ;

ASHFOLD, MNR .

JOURNAL OF CHEMICAL PHYSICS, 1994, 101 (03) :2630-2631

[96] Photochemistry of Saturn's atmosphere -: I.: Hydrocarbon chemistry and comparisons with ISO observations [J].

Moses, JI ;

Bézard, B ;

Lellouch, E ;

Gladstone, GR ;

Feuchtgruber, H ;

Allen, M .

ICARUS, 2000, 143 (02) :244-298

[97] TRIPLET-STATES IN 1,3-BUTADIENE [J].

MOSHER, OA ;

FLICKER, WM ;

KUPPERMANN, A .

CHEMICAL PHYSICS LETTERS, 1973, 19 (03) :332-333

[98] A theoretical investigation of the triplet carbon atom C(3P) plus vinyl radical C2H3(2A′) reaction and thermochemistry of C3Hn (n=1-4) species [J].

Nguyen, TL ;

Mebel, AM ;

Kaiser, RI .

JOURNAL OF PHYSICAL CHEMISTRY A, 2001, 105 (13) :3284-3299

[99] REACTION OF VINYL RADICALS WITH PROPYLENE IN THE GAS-PHASE [J].

NIEDZIELSKI, J ;

GAWLOWSKI, J ;

MAKULSKI, W .

REACTION KINETICS AND CATALYSIS LETTERS, 1981, 18 (3-4) :271-275

[100] VACUUM ULTRAVIOLET PHOTOCHEMISTRY .2. PHOTOLYSISOF ETHYLENE [J].

OKABE, H ;

MCNESBY, JR .

JOURNAL OF CHEMICAL PHYSICS, 1962, 36 (03) :601-&

← 5 6 7 8 9 10 11 12 13 14 →