Microwave-Assisted Cationic Ring-Opening Polymerization of 2-Oxazolines

被引：20
|
作者：
Luef, Klaus P. [1 ,2 ]
Hoogenboom, Richard [3 ]
Schubert, Ulrich S. [4 ,5 ]
Wiesbrock, Frank [1 ]
机构：
[1] Polymer Competence Ctr Leoben GmbH, Roseggerstr 12, A-8700 Leoben, Austria
[2] Graz Univ Technol, Inst Chem & Technol Mat, NAWI Graz, Stremayrgasse 9, A-8010 Graz, Austria
[3] Univ Ghent, Supramol Chem Grp, Dept Organ & Macromol Chem, Krijgslaan 281 S4, B-9000 Ghent, Belgium
[4] Friedrich Schiller Univ Jena, Lab Organ & Macromol Chem IOMC, Humboldtstr 10, D-07743 Jena, Germany
[5] Friedrich Schiller Univ Jena, Jena Ctr Soft Matter JCSM, Philosophenweg 7, D-07743 Jena, Germany
来源：
MICROWAVE-ASSISTED POLYMER SYNTHESIS | 2016年 / 274卷
关键词：
Microwave-assisted polymerization; Non-thermal microwave effects; Poly(2-oxazoline); Post-polymerization modification; Ring-opening polymerization; GLASS-TRANSITION TEMPERATURE; CYCLIC IMINO ETHERS; ONE-POT SYNTHESIS; POLY(2-OXAZOLINE) HYDROGELS; FLUORINATED; 2-PHENYL-2-OXAZOLINES; DIBLOCK COPOLY(2-OXAZOLINE)S; ACCELERATED POLYMERIZATION; HIGH-THROUGHPUT; FUNCTIONALIZED POLY(2-OXAZOLINE)S; BIOMEDICAL APPLICATIONS;
D O I：
10.1007/12_2015_340
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
More than any other polymer class, the synthesis of (co-) poly (2-oxazoline) s has benefited tremendously from the introduction of microwave reactors into chemical laboratories. This review focuses on research activities in the area of (co-) poly(2-oxazoline) s prepared by microwave-assisted syntheses and summarizes the current state-of-the-art for microwave-assisted syntheses of 2-oxazoline monomers, microwave-assisted ring-opening (co-)polymerizations of 2-oxazolines, and prominent examples of post-polymerization modifications of (co-)poly(2-oxazoline) s. Special attention is paid to kinetic analyses of the microwave-assisted polymerization of 2-oxazolines and to the discussion of non-thermal microwave effects.
引用
收藏
页码：183 / 208
页数：26
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