Palladium(0)-Catalyzed Cross-Couplings of 2-Bromophosphinine

被引：7
作者：
Kostenko, Nataliya [1 ]
Ericsson, Cecilia [1 ]
Engqvist, Magnus [1 ]
Gonzalez, Susana Villa [2 ]
Bayer, Annette [1 ]
机构：
[1] Univ Tromso, Dept Chem, N-9037 Tromso, Norway
[2] NTNU, Dept Chem, Trondheim, Norway
来源：
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2013年 / 2013卷 / 22期
关键词：
Phosphorus heterocycles; C-C coupling; Homogeneous catalysis; Phosphinines; Palladium; COORDINATION CHEMISTRY; HOMOGENEOUS CATALYSIS; PYRYLIUM-SALTS; LIGANDS; PHOSPHININE; REACTIVITY; PHOSPHABENZENE; COMPLEXES; 1,3,2-DIAZAPHOSPHININES; HETEROCYCLES;
D O I：
10.1002/ejoc.201300710
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A new Negishi-type cross-coupling of 2-bromophosphinine has been developed. The new method expands the scope of palladium-catalyzed couplings to monobromophosphinines, which have been considered as poor substrates so far. Moreover, aryl-, alkenyl-, and alkynylzinc bromides were found to be effective coupling partners.
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收藏
页码：4756 / 4759
页数：4
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