Estimation of the critical rate of temperature rise for thermal explosion of autocatalytic decomposing reaction of nitrocellulose using non-isothermal DSC

被引：24

作者：

Ning, BK

Hu, RZ ^{[1
]}

Zhang, H

Xia, ZM

Guo, PJ

Liu, R

Lu, GI

Jiang, JY

机构：

[1] Xian Modern Chem Res Inst, Xian 710065, Peoples R China

[2] NW Univ Xian, Dept Chem, Shaanxi Key Lab Physicoinorgan Chem, Xian 710069, Peoples R China

[3] NW Univ Xian, Dept Math, Xian 710069, Peoples R China

[4] Ordnance Engn Inst, Shijiazhuang 05000, Peoples R China

来源：

THERMOCHIMICA ACTA | 2004年 / 416卷 / 1-2期

关键词：

critical rate of temperature rise; DSC; increasing rate of temperatures NC; non-isothermal; thermal explosion;

D O I：

10.1016/j.tca.2003.11.029

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

A method of estimating the critical rate of temperature rise for thermal explosion of empiric-order autocatalytic decomposition reaction system using non-isothermal DSC is presented. Information is obtained on the increasing rate of temperature in nitrocellulose containing 12.97% of nitrogen when the first-order autocatalytic decomposition converts into thermal explosion. (C) 2003 Elsevier B.V. All rights reserved.

引用

页码：47 / 50

页数：4