Alkaloids from Papaver setigerum DC.

被引:27
作者
Slavik, J
Slavikova, L
机构
[1] Biochem. Inst. of Medical Faculty, Masaryk University
关键词
benzylisoquinoline alkaloids; setigerine; setigeridine; papaveraceae;
D O I
10.1135/cccc19961047
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Two new benzylisoquinoline alkaloids of the papaverine type, setigerine (racemic alpha-methoxypapaverine, 1b) and setigeridine (1c), were isolated from Papaver setigerum DC. as the minor constituents. Their structures were established by spectral data and X-ray crystallographic analysis. Papaverine (in) was isolated as the major alkaloid of the plant (0.05 wt.%) besides of less amounts of morphine, codeine and rhoeadine. In a low yield, protopine, cryptopine, thebaine, rhoeagenine, and N-methyl-thebainium (as iodide) were obtained and small quantities of laudanosine, stylopine, isoboldine, scoulerine, papaverrubine A, B, C, D and E, coptisine, corytuberine, and magnoflorine were identified by thin layer chromatography.
引用
收藏
页码:1047 / 1052
页数:6
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