3D printed flow plates for the electrolysis of water: an economic and adaptable approach to device manufacture

被引:145
作者
Chisholm, Greig [1 ]
Kitson, Philip J. [1 ]
Kirkaldy, Niall D. [1 ]
Bloor, Leanne G. [1 ]
Cronin, Leroy [1 ]
机构
[1] Univ Glasgow, Sch Chem, Glasgow G12 8QQ, Lanark, Scotland
基金
英国工程与自然科学研究理事会;
关键词
PEM FUEL-CELLS; CHEMICAL-SYNTHESIS; BIPOLAR PLATES; REACTIONWARE; MICROELECTRODES; PERFORMANCE; CHIP;
D O I
10.1039/c4ee01426j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The electrolysis of water is considered a promising route to the production of hydrogen from renewable energy sources. Electrolysers based on proton exchange membranes (PEMs) have a number of advantages including high current density, high product gas purity and the ability to operate at high pressure. Despite these advantages the high cost of such devices is an impediment to their widespread deployment. A principal factor in this cost are the materials and machining of flow plates for distribution of the liquid reagents and gaseous products in the electrochemical cell. We demonstrate the production and operation of a PEM electrolyser constructed from silver coated 3D printed components fabricated from polypropylene. This approach allows construction of light weight, low cost electrolysers and the rapid prototyping of flow field design. Furthermore we provide data on the operation of this electrolyser wherein we show that performance is excellent for a first generation device in terms of overall efficiency, internal resistances and current-voltage response. This development opens the door to the fabrication of light weight and cheap electrolysers as well as related electrochemical devices such as flow batteries and fuel cells.
引用
收藏
页码:3026 / 3032
页数:7
相关论文
共 30 条
  • [1] Omnidirectional Printing of Flexible, Stretchable, and Spanning Silver Microelectrodes
    Ahn, Bok Y.
    Duoss, Eric B.
    Motala, Michael J.
    Guo, Xiaoying
    Park, Sang-Il
    Xiong, Yujie
    Yoon, Jongseung
    Nuzzo, Ralph G.
    Rogers, John A.
    Lewis, Jennifer A.
    [J]. SCIENCE, 2009, 323 (5921) : 1590 - 1593
  • [2] Ayers K., 2012, ECS T, V41, P15, DOI DOI 10.1149/1.3684798
  • [3] Research Advances Towards Low Cost, High Efficiency PEM Electrolysis
    Ayers, K. E.
    Anderson, E. B.
    Capuano, C. B.
    Carter, B. D.
    Dalton, L. T.
    Hanlon, G.
    Manco, J.
    Niedzwiecki, M.
    [J]. POLYMER ELECTROLYTE FUEL CELLS 10, PTS 1 AND 2, 2010, 33 (01): : 3 - 15
  • [4] PEM electrolysis for production of hydrogen from renewable energy sources
    Barbir, F
    [J]. SOLAR ENERGY, 2005, 78 (05) : 661 - 669
  • [5] Energetic evaluation of high pressure PEM electrolyzer systems for intermediate storage of renewable energies
    Bensmann, B.
    Hanke-Rauschenbach, R.
    Arias, I. K. Pena
    Sundmacher, K.
    [J]. ELECTROCHIMICA ACTA, 2013, 110 : 570 - 580
  • [6] A comprehensive review on PEM water electrolysis
    Carmo, Marcelo
    Fritz, David L.
    Merge, Juergen
    Stolten, Detlef
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2013, 38 (12) : 4901 - 4934
  • [7] Uncommon patterns in Nafion films loaded with silver nanoparticles
    Domenech, Berta
    Munoz, Maria
    Muraviev, Dmitri N.
    Macanas, Jorge
    [J]. CHEMICAL COMMUNICATIONS, 2014, 50 (36) : 4693 - 4695
  • [8] Patterning: Principles and some new developments
    Geissler, M
    Xia, YN
    [J]. ADVANCED MATERIALS, 2004, 16 (15) : 1249 - 1269
  • [9] Harrison R. R. K. W., 2010, NRELCP55047302
  • [10] Multi-directional micro-switching valve chip with rotary mechanism
    Hasegawa, Tadahiro
    Nakashima, Kenichiro
    Omatsu, Fumiyuki
    Ikuta, Koji
    [J]. SENSORS AND ACTUATORS A-PHYSICAL, 2008, 143 (02) : 390 - 398