High efficiency flexible perovskite solar cells using superior low temperature TiO2

被引:496
作者
Yang, Dong [1 ]
Yang, Ruixia [2 ]
Zhang, Jing [2 ]
Yang, Zhou [1 ]
Liu, Shengzhong [1 ,2 ]
Li, Can [2 ]
机构
[1] Shaanxi Normal Univ, Inst Adv Energy Mat, Sch Mat Sci & Engn, Key Lab Appl Surface & Colloid Chem,Natl Minist E, Xian 710119, Peoples R China
[2] Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China
关键词
HALIDE PEROVSKITES; HYBRID PEROVSKITE; BLOCKING LAYERS; FABRICATION; CH3NH3PBI3; FILMS; DEPOSITION; LENGTHS;
D O I
10.1039/c5ee02155c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A process is developed to prepare a very dense TiO2 layer using magnetron sputtering at room temperature. It is found that the film is amorphous in nature, offering faster electron transport, reduced transfer resistance and better performance for electron extraction from the perovskite absorber layer. It is these superior electronic properties that makes it possible for us to achieve 15.07% efficiency flexible perovskite solar cells, on a respectably large area >10 mm(2). It is the highest efficiency reported to date for the flexible perovskite devices.
引用
收藏
页码:3208 / 3214
页数:7
相关论文
共 54 条
[1]   Using a two-step deposition technique to prepare perovskite (CH3NH3PbI3) for thin film solar cells based on ZrO2 and TiO2 mesostructures [J].
Bi, Dongqin ;
Moon, Soo-Jin ;
Haggman, Leif ;
Boschloo, Gerrit ;
Yang, Lei ;
Johansson, Erik M. J. ;
Nazeeruddin, Mohammad K. ;
Graetzel, Michael ;
Hagfeldt, Anders .
RSC ADVANCES, 2013, 3 (41) :18762-18766
[2]   Sequential deposition as a route to high-performance perovskite-sensitized solar cells [J].
Burschka, Julian ;
Pellet, Norman ;
Moon, Soo-Jin ;
Humphry-Baker, Robin ;
Gao, Peng ;
Nazeeruddin, Mohammad K. ;
Graetzel, Michael .
NATURE, 2013, 499 (7458) :316-+
[3]   High performance hybrid solar cells sensitized by organolead halide perovskites [J].
Cai, Bing ;
Xing, Yedi ;
Yang, Zhou ;
Zhang, Wen-Hua ;
Qiu, Jieshan .
ENERGY & ENVIRONMENTAL SCIENCE, 2013, 6 (05) :1480-1485
[4]   Planar Heterojunction Perovskite Solar Cells via Vapor-Assisted Solution Process [J].
Chen, Qi ;
Zhou, Huanping ;
Hong, Ziruo ;
Luo, Song ;
Duan, Hsin-Sheng ;
Wang, Hsin-Hua ;
Liu, Yongsheng ;
Li, Gang ;
Yang, Yang .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (02) :622-625
[5]   Layer-by-Layer Growth of CH3NH3PbI3-xClx for Highly Efficient Planar Heterojunction Perovskite Solar Cells [J].
Chen, Yonghua ;
Chen, Tao ;
Dai, Liming .
ADVANCED MATERIALS, 2015, 27 (06) :1053-1059
[6]   Scalable fabrication of efficient organolead trihalide perovskite solar cells with doctor-bladed active layers [J].
Deng, Yehao ;
Peng, Edwin ;
Shao, Yuchuan ;
Xiao, Zhengguo ;
Dong, Qingfeng ;
Huang, Jinsong .
ENERGY & ENVIRONMENTAL SCIENCE, 2015, 8 (05) :1544-1550
[7]   Low-temperature fabrication of dye-sensitized solar cells by transfer of composite porous layers [J].
Dürr, M ;
Schmid, A ;
Obermaier, M ;
Rosselli, S ;
Yasuda, A ;
Nelles, G .
NATURE MATERIALS, 2005, 4 (08) :607-611
[8]   Neutral Color Semitransparent Microstructured Perovskite Solar Cells [J].
Eperon, Giles E. ;
Burlakov, Victor M. ;
Goriely, Alain ;
Snaith, Henry J. .
ACS NANO, 2014, 8 (01) :591-598
[9]   Maximizing the emissive properties of CH3NH3PbBr3 perovskite nanoparticles [J].
Gonzalez-Carrero, Soranyel ;
Galian, Raquel E. ;
Perez-Prieto, Julia .
JOURNAL OF MATERIALS CHEMISTRY A, 2015, 3 (17) :9187-9193
[10]   Lead-free solid-state organic-inorganic halide perovskite solar cells [J].
Hao, Feng ;
Stoumpos, Constantinos C. ;
Duyen Hanh Cao ;
Chang, Robert P. H. ;
Kanatzidis, Mercouri G. .
NATURE PHOTONICS, 2014, 8 (06) :489-494