Open Pentameric Calixarene Nanocage

被引：42
作者：
Su, Kongzhao [1 ,2 ]
Jiang, Feilong [1 ]
Qian, Jinjie [1 ,2 ]
Wu, Mingyan [1 ]
Gai, Yanli [1 ,2 ]
Pan, Jie [1 ,2 ]
Yuan, Daqiang [1 ]
Hong, Maochun [1 ]
机构：
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
来源：
INORGANIC CHEMISTRY | 2014年 / 53卷 / 01期
关键词：
COORDINATION CAGES; CRYSTAL-STRUCTURES; COMPLEXES; CHEMISTRY; CLUSTERS; SQUARE; DY; LN;
D O I：
10.1021/ic4024184
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel open helmetlike coordination cage has been synthesized based on Co-4-calixarene shuttlecock-like secondary building units and in situ generated phosphate anions, where the opening of the cage comprises a large 16-membered ring. The above unprecedented Co-20 nanocage presents the first pentameric calixarene coordination compound. Sorption behavior and magnetic properties are also investigated.
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收藏
页码：18 / 20
页数：3
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