Direct imaging of crystal structure and defects in metastable Ge2Sb2Te5 by quantitative aberration-corrected scanning transmission electron microscopy

被引:47
作者
Ross, Ulrich [1 ]
Lotnyk, Andriy [1 ]
Thelander, Erik [1 ]
Rauschenbach, Bernd [1 ]
机构
[1] Leibniz Inst Surface Modificat, D-04318 Leipzig, Germany
关键词
PHASE-CHANGE MATERIALS; AB-INITIO; TRANSITIONS; VACANCIES; CRYSTALLIZATION; DESIGN; MEMORY; FILMS; TE; GE;
D O I
10.1063/1.4869471
中图分类号
O59 [应用物理学];
学科分类号
摘要
Knowledge about the atomic structure and vacancy distribution in phase change materials is of foremost importance in order to understand the underlying mechanism of fast reversible phase transformation. In this Letter, by combining state-of-the-art aberration-corrected scanning transmission electron microscopy with image simulations, we are able to map the local atomic structure and composition of a textured metastable Ge2Sb2Te5 thin film deposited by pulsed laser deposition with excellent spatial resolution. The atomic-resolution scanning transmission electron microscopy investigations display the heterogeneous defect structure of the Ge2Sb2Te5 phase. The obtained results are discussed. Highly oriented Ge2Sb2Te5 thin films appear to be a promising approach for further atomic-resolution investigations of the phase change behavior of this material class. (C) 2014 AIP Publishing LLC.
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页数:5
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