Direct growth of nickel-cobalt oxide nanosheet arrays on carbon nanotubes integrated with binder-free hydrothermal carbons for fabrication of high performance asymmetric supercapacitors

A high performance asymmetric supercapacitor (ASC) has been fabricated by using nickel oxide-cobalt oxide nanosheets (NiO-CoO NSs), which were directly grown on carbon nanotubes (CNTs) and hydrothermal carbon spheres (HTCs) as positive and negative electrodes, respectively. Both electrode materials are binder-free prepared by using a catalytic chemical vapour deposition (CVD) approach followed by a facile hydrothermal method for cathode and a one-step environmental-friendly route called hydrothermal carbonization for anode. Using NiO-CoO NSs@CNTs and HTCs, which were directly grown on Ni foam, not only leads to a very small equivalent series resistance, but also provides an impressive capacitive performance. The assembled ASC exhibits remarkable capacitive performance over a broad operational potential window ensuring outstanding energy densities (84.625 Wh. kg(-1) at 3 A g(-1)). Other noteworthy features of the prepared supercapacitor include its superior power density (7810 W kg(-1) at 9.5 A g(-1)) and cycling stability with capacitance retention almost over 80% after 6000 cycles. These electrochemical results point to NiO-CoO NSs@CNTs-Ni//HTCs-Ni based asymmetric supercapacitors as a promising remedy for energy crisis and environmental deterioration problems.