Coexistence of chiral hydrophilic and achiral hydrophobic channels in one multi-helical-array metal-organic framework incorporating helical water cluster chains

被引：121
作者：
Zang, Shuangquan [1 ]
Su, Yang [1 ]
Duan, Chunying [1 ]
Li, Yizhi [1 ]
Zhu, Huizhen [1 ]
Meng, Qingjin [1 ]
机构：
[1] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Sch Chem Engn, Nanjing 210093, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2006年 / 48期
关键词：
D O I：
10.1039/b611994h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel host-guest metal-organic compound with both chiral hydrophilic and achiral hydrophobic channels has been obtained through the reaction of Cd(II) ion and a versatile asymmetrical ligand of H(4)bptc (H(4)bptc = 1,19-biphenyl-2,29,3,39-tetracarboxylic acid) based on hydro(solvo) thermal reactions.
引用
收藏
页码：4997 / 4999
页数：3
相关论文
共 66 条
[1]   Zinc saccharate: A robust, 3D coordination network with two types of isolated, parallel channels, one hydrophilic and the other hydrophobic [J].
Abrahams, BF ;
Moylan, M ;
Orchard, SD ;
Robson, R .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (16) :1848-1851
[2]  
Abrahams BF, 1998, ANGEW CHEM INT EDIT, V37, P2656, DOI 10.1002/(SICI)1521-3773(19981016)37:19<2656::AID-ANIE2656>3.0.CO
[3]  
2-M
[4]   Structural characterization of an enantiopure hydroxo-bridged binuclear iron(III) complex with empty one-dimensional helical channels [J].
Alam, MA ;
Nethaji, M ;
Ray, M .
INORGANIC CHEMISTRY, 2005, 44 (05) :1302-1308
[5]   Artificial molecular double-stranded helices [J].
Albrecht, M .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (40) :6448-6451
[6]   Let's twist again - Double-stranded, triple-stranded, and circular helicates [J].
Albrecht, M .
CHEMICAL REVIEWS, 2001, 101 (11) :3457-3497
[7]   An intermolecular (H2O)10 cluster in a solid-state supramolecular complex [J].
Barbour, LJ ;
Orr, GW ;
Atwood, JL .
NATURE, 1998, 393 (6686) :671-673
[8]  
Biradha K, 1999, ANGEW CHEM INT EDIT, V38, P492, DOI 10.1002/(SICI)1521-3773(19990215)38:4<492::AID-ANIE492>3.0.CO
[9]  
2-#
[10]   A three-dimensional nanoporous flexible network of 'square-planar' copper(II) centres with an unusual topology [J].
Carlucci, L ;
Cozzi, N ;
Ciani, G ;
Moret, M ;
Proserpio, DM ;
Rizzato, S .
CHEMICAL COMMUNICATIONS, 2002, (13) :1354-1355
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