Ultrastable hydrogen evolution electrocatalyst derived from phosphide postmodified metal-organic frameworks

被引：76

作者：

Cheng, Yuanhui ^{[1
]}

Guo, Jianing ^{[1
]}

Huang, Yan ^{[1
]}

Liao, Zhijian ^{[1
]}

Xiang, Zhonghua ^{[1
]}

机构：

[1] Beijing Univ Chem Technol, State Key Lab Organ Inorgan Composites, Beijing 100029, Peoples R China

来源：

NANO ENERGY | 2017年 / 35卷

基金：

北京市自然科学基金;

关键词：

Hydrogen evolution reaction; Electrocatalyst; Metal phosphide; Doped carbon; OXYGEN REDUCTION REACTION; EFFICIENT ELECTROCATALYST; MOLYBDENUM PHOSPHIDE; GENERATING HYDROGEN; ASTERISK-ASTERISK; NEUTRAL SOLUTIONS; CARBON NANOTUBES; NANOPARTICLES; WATER; PERFORMANCE;

D O I：

10.1016/j.nanoen.2017.03.028

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Developing non-precious metal catalyst with high activity, good stability and low cost for electrocatalytic hydrogen evolution reaction (HER) is critical for hydrogen product from water splitting. Here, we proposed a facile and effective approach to in situ synthesize highly efficient and ultrastable iron phosphide hybrids anchored inside a hollow N-P codoped carbon derived from MIL-101-NH2-Fe-P (not only acting as multifunctional precursor but also nanoscale confined space during pyrolysis) via one-step method for HER. The newly developed FexP@NPC catalyst exhibits high electrocatalytic activity and shows a nearly constant voltage with only less 0.1% increase at 10 mA cm(-2) after 90 h in full water splitting cell with high Faradaic efficiency of near 100% and keep very similar level even after shelving 10 days.

引用

页码：115 / 120

页数：6

共 49 条

[11] The Chemistry and Applications of Metal-Organic Frameworks [J].

Furukawa, Hiroyasu ;

Cordova, Kyle E. ;

O'Keeffe, Michael ;

Yaghi, Omar M. .

SCIENCE, 2013, 341 (6149) :974-+

[12] Examination of the bonding in binary transiton-metal monophosphides MP (M = Cr, Mn, Fe, Co) by x-ray photoelectron spectroscopy [J].

Grosvenor, AP ;

Wik, SD ;

Cavell, RG ;

Mar, A .

INORGANIC CHEMISTRY, 2005, 44 (24) :8988-8998

[13] Sustainable fermentative hydrogen production: challenges for process optimisation [J].

Hawkes, FR ;

Dinsdale, R ;

Hawkes, DL ;

Hussy, I .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2002, 27 (11-12) :1339-1347

[14] Cobalt phosphide nanorods as an efficient electrocatalyst for the hydrogen evolution reaction [J].

Huang, Zhipeng ;

Chen, Zhongzhong ;

Chen, Zhibo ;

Lv, Cuncai ;

Humphrey, Mark G. ;

Zhang, Chi .

NANO ENERGY, 2014, 9 :373-382

[15] CoSe2 Nanoparticles Grown on Carbon Fiber Paper: An Efficient and Stable Electrocatalyst for Hydrogen Evolution Reaction [J].

Kong, Desheng ;

Wang, Haotian ;

Lu, Zhiyi ;

Cui, Yi .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (13) :4897-4900

[16] MOF-derived nanostructured cobalt phosphide assemblies for efficient hydrogen evolution reaction [J].

Li, Lili ;

Li, Xingyue ;

Ai, Lunhong ;

Jiang, Jing .

RSC ADVANCES, 2015, 5 (110) :90265-90271

[17] New Heterometallic Zirconium Metalloporphyrin Frameworks and Their Heteroatom-Activated High-Surface-Area Carbon Derivatives [J].

Lin, Qipu ;

Bu, Xianhui ;

Kong, Aiguo ;

Mao, Chengyu ;

Zhao, Xiang ;

Bu, Fei ;

Feng, Pingyun .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2015, 137 (06) :2235-2238

[18] Electrocatalytic hydrogen evolution using amorphous tungsten phosphide nanoparticles [J].

McEnaney, Joshua M. ;

Crompton, J. Chance ;

Callejas, Juan F. ;

Popczun, Eric J. ;

Read, Carlos G. ;

Lewis, Nathan S. ;

Schaak, Raymond E. .

CHEMICAL COMMUNICATIONS, 2014, 50 (75) :11026-11028

[19] X-RAY PHOTOELECTRON-SPECTRA AND BONDING IN TRANSITION-METAL PHOSPHIDES [J].

MYERS, CE ;

FRANZEN, HF ;

ANDEREGG, JW .

INORGANIC CHEMISTRY, 1985, 24 (12) :1822-1824

[20] Highly Active Electrocatalysis of the Hydrogen Evolution Reaction by Cobalt Phosphide Nanoparticles** [J].

Popczun, Eric J. ;

Read, Carlos G. ;

Roske, Christopher W. ;

Lewis, Nathan S. ;

Schaak, Raymond E. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014, 53 (21) :5427-5430

← 1 2 3 4 5 →