The Gas-Phase Ammoxidation of n-Hexane to Unsaturated C6 Dinitriles, Intermediates for Hexamethylenediamine Synthesis

被引：0

作者：

Ballarini, Nicola ^{[1
]}

Battisti, Andrea ^{[1
]}

Castelli, Alessandro ^{[1
]}

Cavani, Fabrizio ^{[1
]}

Lucarelli, Carlo ^{[1
]}

Marion, Philippe

Righi, Paolo

Spadoni, Cristian ^{[1
]}

机构：

[1] Univ Bologna, Dipartimento Chim Ind & Mat, Viale Risorgimento 4, I-40136 Bologna, Italy

来源：

CATALYSIS OF ORGANIC REACTIONS | 2009年 / 123卷

关键词：

PROPANE AMMOXIDATION; MIXED OXIDES; CATALYSTS; ADIPONITRILE;

D O I：

暂无

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

This chapter reports about an investigation on the catalytic gas-phase ammoxidation of n-hexane aimed at the production of 1,6-C-6 dinitriles, precursors for the synthesis of hexamethylenediamine. Catalysts tested were those also active and selective ill the ammoxidation of propane to acrylonitrile: rutile-type V/Sb and Sn/V/Nb/Sb mixed oxides. Several N-containing compounds formed; however, the selectivity to cyano-containing aliphatic linear C-6 compounds was low, due to the relevant contribution of side reactions such as combustion, cracking and formation of heavy compounds.

引用

页码：357 / +

页数：2

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