Yield stress changes induced by water in polyamide 6: Characterization and modeling

被引：66

作者：

Le Gac, Pierre Yves ^{[1
]}

Arhant, Mael ^{[1
]}

Le Gall, Maelenn ^{[1
]}

Davies, Peter ^{[1
]}

机构：

[1] IFREMER, Ctr Bretagne, Marine Struct Lab, F-29280 Plouzane, France

来源：

POLYMER DEGRADATION AND STABILITY | 2017年 / 137卷

关键词：

Yield stress; Water; Polyamide; Plasticization; Prediction; SOLVENT SYSTEMS; TEMPERATURE; BEHAVIOR; DIFFUSION; POLYMER; PREDICTION; ABSORPTION; TRANSPORT;

D O I：

10.1016/j.polymdegradstab.2017.02.003

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

This paper considers the effect of water content on mechanical properties of polyamide 6 when used in a humid environment. First an experimental section presents the tensile behavior of polyamide with different amounts of water, with and without a through-thickness water gradient. Water profiles are introduced by immersion in sea water at 25 degrees C. The effect of testing temperature is also investigated in order to consider the influence of macromolecular chain mobility on the mechanical behavior. Then, in a second section, modeling of yield stress is proposed based on physical considerations. This can be used for life time prediction of PA6 in humid environment when plasticization is the main degradation mechanism. (C) 2017 Elsevier Ltd. All rights reserved.

引用

页码：272 / 280

页数：9

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