Catalytic growth of carbon nanotubes and nanofibers on vermiculite to produce floatable hydrophobic "nanosponges" for oil spill remediation

被引:82
作者
Moura, Flavia C. C. [1 ]
Lago, Rochel M. [2 ]
机构
[1] Univ Fed Ouro Preto, Dept Quim ICEB, BR-35400000 Ouro Preto, MG, Brazil
[2] Univ Fed Minas Gerais, Dept Quim ICEx, BR-31270901 Belo Horizonte, MG, Brazil
关键词
Carbon nanotubes; Vermiculite; Adsorbents; Environmental application;
D O I
10.1016/j.apcatb.2009.04.003
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this work, chemical vapour deposition (CVD) synthesis of carbon nanotubes (CNT) and nanofibers on the surface of expanded vermiculite (EV) was used to produce a highly hydrophobic floatable absorvent to remove oil spilled on water. XRD, SEM, TG and Raman spectroscopy showed that the carbon nanotubes and nanofibers grow on FeMo catalyst impregnated on the EV surface to form a "sponge structure". As a result of these carbonaceous nanosponges the absorption of different oils remarkably increased ca. 600% with a concomitant strong decrease of the undesirable water absorption. (C) 2009 Published by Elsevier B.V.
引用
收藏
页码:436 / 440
页数:5
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