Metallosurfactants: Interfaces and micelles

被引：105
作者：
Griffiths, P. C.
Fallis, I. A.
Chuenpratoom, T.
Watanesk, R.
机构：
[1] Cardiff Univ, Sch Chem, Cardiff CF10 3AT, Wales
[2] Chiang Mai Univ, Fac Sci, Dept Chem, Chiang Mai 50200, Thailand
来源：
ADVANCES IN COLLOID AND INTERFACE SCIENCE | 2006年 / 122卷 / 1-3期
基金：
英国工程与自然科学研究理事会;
关键词：
aggregation; adsorption; surface layers; metal ion; self-association;
D O I：
10.1016/j.cis.2006.06.010
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Incorporating a metal cation as an integral component of the headgroup of a surfactant - a metallosurfactant - offers a route to concentrate these ions and their associated functionality at interfaces. To reduce the lability of the metal, various chelating or macrocyclic ligands may be employed leading to a family of homologous series of related metallosurfactants with a structural diversity that is arguably broader than is inherently possible with conventional surfactants. This review discusses the small number of key papers that are quantifying the physico-chemical properties of metallosurfactants and highlights their "classical" as well as "non-classical" surfactant behaviour, providing an insight into the structure of micelles and films formed from these novel materials. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码：107 / 117
页数：11
相关论文
共 49 条
[11]   Functional liquid-crystalline materials based on ferrocene [J].
Chuard, T ;
Deschenaux, R .
CHIMIA, 2003, 57 (10) :597-600
[12]   High-activity heterogeneous catalysts prepared in one step from the mesophases of metallosurfactants [J].
Danks, MJ ;
Jervis, HB ;
Nowotny, M ;
Zhou, WZ ;
Maschmeyer, TA ;
Bruce, DW .
CATALYSIS LETTERS, 2002, 82 (1-2) :95-98
[13]   Switchable mesomorphic materials based on the ferrocene-ferrocenium redox system: Electron-transfer-generated columnar liquid-crystalline phases [J].
Deschenaux, R ;
Schweissguth, M ;
Vilches, MT ;
Levelut, AM ;
Hautot, D ;
Long, GJ ;
Luneau, D .
ORGANOMETALLICS, 1999, 18 (26) :5553-5559
[14]  
DESCHENAUX R, 1993, CHIMIA, V47, P206
[15]  
DESCHENAUX R, 1995, FERROCENES, P471, DOI 10.1002/9783527615599.ch09
[16]   Lyotropic metallomesogens [J].
Donnio, B .
CURRENT OPINION IN COLLOID & INTERFACE SCIENCE, 2002, 7 (5-6) :371-394
[17]   A ferrocene-containing carbohydrate surfactant: Thermotropic and lyotropic phase behavior [J].
Donnio, B ;
Seddon, JM ;
Deschenaux, R .
ORGANOMETALLICS, 2000, 19 (16) :3077-3081
[18]  
Fallis I.A., 1998, J CHEM SOC CHEM COMM, V6, P665
[19]   STRUCTURE OF N1-(3-PHENOXYPROPYL)-4,7-DIAZA-1-AZONIATRICYCLO[5.2.1.04,10]DECANE BROMIDE HYDRATE [J].
FARRUGIA, LJ ;
LOVATT, PA ;
PEACOCK, RD .
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1993, 49 :2164-2165
[20]   Mesostructured fluids:: supra aggregates made of interdigitated reverse micelles [J].
Filankembo, A ;
André, P ;
Lisiecki, I ;
Petit, C ;
Gulik-Krzywicki, T ;
Ninham, BW ;
Pileni, MP .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2000, 174 (1-2) :221-232
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