Metallosurfactants: Interfaces and micelles

被引：105
作者：
Griffiths, P. C.
Fallis, I. A.
Chuenpratoom, T.
Watanesk, R.
机构：
[1] Cardiff Univ, Sch Chem, Cardiff CF10 3AT, Wales
[2] Chiang Mai Univ, Fac Sci, Dept Chem, Chiang Mai 50200, Thailand
来源：
ADVANCES IN COLLOID AND INTERFACE SCIENCE | 2006年 / 122卷 / 1-3期
基金：
英国工程与自然科学研究理事会;
关键词：
aggregation; adsorption; surface layers; metal ion; self-association;
D O I：
10.1016/j.cis.2006.06.010
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Incorporating a metal cation as an integral component of the headgroup of a surfactant - a metallosurfactant - offers a route to concentrate these ions and their associated functionality at interfaces. To reduce the lability of the metal, various chelating or macrocyclic ligands may be employed leading to a family of homologous series of related metallosurfactants with a structural diversity that is arguably broader than is inherently possible with conventional surfactants. This review discusses the small number of key papers that are quantifying the physico-chemical properties of metallosurfactants and highlights their "classical" as well as "non-classical" surfactant behaviour, providing an insight into the structure of micelles and films formed from these novel materials. (c) 2006 Elsevier B.V. All rights reserved.
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收藏
页码：107 / 117
页数：11
相关论文
共 49 条
[1]  
Andersson M, 2003, SELF-ASSEMBLY, P105
[2]   Supra-aggregates [J].
André, P ;
Ninham, BW ;
Pileni, MP .
ADVANCES IN COLLOID AND INTERFACE SCIENCE, 2001, 89 :155-167
[3]   Small-angle scattering study of TAC8: A surfactant with cation complexing potential [J].
Arleth, L ;
Posselt, D ;
Gazeau, D ;
Larpent, C ;
Zemb, T ;
Mortensen, K ;
Pedersen, JS .
LANGMUIR, 1997, 13 (07) :1887-1896
[4]   COUNTERION-DRIVEN SPHERE TO CYLINDER TRANSITION IN REVERSE MICELLES - A SMALL-ANGLE X-RAY-SCATTERING AND CONDUCTOMETRIC STUDY [J].
BARDEZ, E ;
VY, NC ;
ZEMB, T .
LANGMUIR, 1995, 11 (09) :3374-3381
[5]   Lanthanide-containing reversed micelles: A structural and luminescence study [J].
Beeby, A ;
Clarkson, IM ;
Eastoe, J ;
Faulkner, S ;
Warne, B .
LANGMUIR, 1997, 13 (22) :5816-5819
[6]   Surface and aggregation behavior of aqueous solutions of Ru(II) metallosurfactants:: 4.: Effect of chain number and orientation on the aggregation of [Ru(bipy)2(bipy′]Cl2 complexes [J].
Bowers, J ;
Amos, KE ;
Bruce, DW ;
Heenan, RK .
LANGMUIR, 2005, 21 (13) :5696-5706
[7]   Surface and aggregation behavior of aqueous solutions of Ru(II) metallosurfactants.: 3.: Effect of chain number and orientation on the structure of adsorbed films of [Ru(bipy)2(bipy′)]Cl2 complexes [J].
Bowers, J ;
Amos, KE ;
Bruce, DW ;
Webster, JRP .
LANGMUIR, 2005, 21 (04) :1346-1353
[8]   Surface and aggregation behavior of aqueous solutions of Ru(II) metallosurfactants:: 2.: Adsorbed films of [Ru(biPY)2(bipy′)][Cl]2 complexes [J].
Bowers, J ;
Danks, MJ ;
Bruce, DW ;
Webster, JRP .
LANGMUIR, 2003, 19 (02) :299-305
[9]   Surface and aggregation behavior of aqueous solutions of Ru(II) metallosurfactants:: 1.: Micellization of [Ru(bipy)2(bipy′)][Cl]2 complexes [J].
Bowers, J ;
Danks, MJ ;
Bruce, DW .
LANGMUIR, 2003, 19 (02) :292-298
[10]   Synthesis, characterization, Langmuir-Blodgett film-forming properties, and second-harmonic-generation studies of ruthenium(II) complexes with long hydrocarbon chains [J].
Chu, BWK ;
Yam, VWW .
INORGANIC CHEMISTRY, 2001, 40 (14) :3324-3329
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