Hydrothermal synthesis of monodispersed LiFePO4 cathode materials in alcohol-water mixed solutions

被引：15

作者：

Zhang, Chunhua ^{[1
]}

Huang, Xiang ^{[1
]}

Yin, Yansheng ^{[1
]}

Dai, Jinhui ^{[1
]}

Zhu, Zhibin ^{[1
]}

机构：

[1] Ocean Univ China, Inst Mat Sci & Engn, Qingdao 266100, Peoples R China

来源：

CERAMICS INTERNATIONAL | 2009年 / 35卷 / 07期

关键词：

Hydrothermal synthesis; Dielectric tuner; Monodispersed particles; Cathode materials; ELECTROCHEMICAL-BEHAVIOR; PARTICLE FORMATION; PHOSPHO-OLIVINES; LITHIUM;

D O I：

10.1016/j.ceramint.2009.02.024

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Monodispersed LiFePO4 powders were prepared by thermal decomposition of Fe(II)-citric acid complex precursor and application of isopropanol as a dielectric constant tuner. The powders morphology was greatly influenced by the volume ratio of isopropanol to water (RH ratio). Monodispersed short rod-like LiFePO4 crystals were obtained when RH ratio was 1.0, while column-like LiFePO4 particles composed of much smaller crystals were produced when isopropanol was absent. (C) 2009 Elsevier Ltd and Techna Group S.r.l. All rights reserved.

引用

页码：2979 / 2982

页数：4

共 14 条

[1]

Brinker C.J., 1990, SOL GEL SCI PHYS CHE, P235

[2] Reducing carbon in LiFePO4/C composite electrodes to maximize specific energy, volumetric energy, and tap density [J].

Chen, ZH ;

Dahn, JR .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2002, 149 (09) :A1184-A1189

[3] Electronically conductive phospho-olivines as lithium storage electrodes [J].

Chung, SY ;

Bloking, JT ;

Chiang, YM .

NATURE MATERIALS, 2002, 1 (02) :123-128

[4] A novel concept for the synthesis of an improved LiFePO4 lithium battery cathode [J].

Croce, F ;

D'Epifanio, A ;

Hassoun, J ;

Deptula, A ;

Olczac, T ;

Scrosati, B .

ELECTROCHEMICAL AND SOLID STATE LETTERS, 2002, 5 (03) :A47-A50

[5] Comparison between different LiFePO4 synthesis routes and their influence on its physico-chemical properties [J].

Franger, S ;

Le Cras, F ;

Bourbon, C ;

Rouault, H .

JOURNAL OF POWER SOURCES, 2003, 119 :252-257

[6] Sol-gel and ultrafine particle formation via dielectric tuning of inorganic salt-alcohol-water solutions [J].

Hu, MZC ;

Payzant, EA ;

Byers, CH .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2000, 222 (01) :20-36

[7] Approaching theoretical capacity of LiFePO4 at room temperature at high rates [J].

Huang, H ;

Yin, SC ;

Nazar, LF .

ELECTROCHEMICAL AND SOLID STATE LETTERS, 2001, 4 (10) :A170-A172

[8] Hydrothermal synthesis of LiNiVO4 cathode material for lithium ion batteries [J].

Lu, CH ;

Lee, WC ;

Liou, SJ ;

Fey, GTK .

JOURNAL OF POWER SOURCES, 1999, 81 :696-699

[9] Hydrothermal synthesis and electrochemical behavior of orthorhombic LiMnO2 [J].

Myung, ST ;

Komaba, S ;

Kumagai, N .

ELECTROCHIMICA ACTA, 2002, 47 (20) :3287-3295

[10] Phospho-olivines as positive-electrode materials for rechargeable lithium batteries [J].

Padhi, AK ;

Nanjundaswamy, KS ;

Goodenough, JB .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1997, 144 (04) :1188-1194

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