First triangular carboxylate cluster with the Fe(II)Fe(II)Fe(II) metal core

被引：12

作者：

Kiskin, MA

Fomina, IG

Aleksandrov, GG

Sidorov, AA

Novotortsev, VM

Shvedenkov, YG

Eremenko, IL

Moiseev, II

机构：

[1] Russian Acad Sci, NS Kurnakov Gen & Inorgan Chem Inst, Moscow 119991, Russia

[2] Russian Acad Sci, Int Tomog Ctr, Siberian Branch, Novosibirsk 630090, Russia

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2004年 / 7卷 / 06期

基金：

俄罗斯基础研究基金会;

关键词：

pivalate iron(II) clusters; X-ray structure; magnetic properties;

D O I：

10.1016/j.inoche.2004.03.024

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

First iron(II) carboxylate cluster with the triangular metal core K[Fe-3(mu(3)-OH)(OOCCMe3)(6)(HOOCCMe3)(3)] (1) has been isolated from the reaction between FeSO4 . 7H(2)O and KOOCCMe3 in the presence of the excess of pivalic acid in MeCN. The X-ray data and magnetic study show the complex molecular unit to be constructed of the Fe(II) atoms. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：734 / 736

页数：3

共 11 条

[1]

[Anonymous], 1997, SMART CONTR SAINT IN

[2] CRYSTAL-STRUCTURE AND MASS-SPECTRUM OF MU3-OXO-HEXAKIS(MU-TRIMETHYL-ACETATO)-TRISMETHANOLTRI-IRON(III) CHLORIDE, A TRINUCLEAR BASIS IRON(III) CARBOXYLATE [J].