Boosting the performance of ZnO microrod metal-semiconductor-metal photodetectors via surface capping of thin amorphous Al2O3 shell layer

1D ZnO nanostructures have been widely explored due to their potential applications in ultraviolet (UV) region photodetectors because of their unique structural and optoelectronic properties. However, a large number of surface defect states leading to a noticeable dark current hinders their practical applications in UV photodetection. In this work, we have shown improved ZnO/Al(2)O(3)core-shell microrod photodetectors, whose performance is significantly enhanced by defect passivation and the introduction of trap states by atomic layer deposition grown thin amorphous Al(2)O(3)shell layer, as evidenced by steady-state and transient photoluminescence investigations. The photodetectors demonstrated suppressed dark current and increased photocurrent after capping the Al(2)O(3)layer. Specifically, the ZnO/Al(2)O(3)core-shell microrod photodetector exhibited a photoresponsivity as high as 0.019 A/(W cm(-2)) with the dark current as low as similar to 1 x 10(-11)A, and a highI(light)/I(dark)ratio of similar to 10(4)under relatively weak light illumination (similar to 10 mu W cm(-2)). The results presented in this work provide valuable pathways to boost the performance of 1D ZnO microrod-based photodetectors for future practical applications.