semiconductors;
crystal growth;
luminescence;
electronic states (localized);
D O I:
10.1016/j.jallcom.2003.06.012
中图分类号:
O64 [物理化学(理论化学)、化学物理学];
学科分类号:
070304 ;
081704 ;
摘要:
Photoluminescence characteristics as a function of temperature were investigated for Zn1-xMgxSe (0 < x < 0.63) and Cd1-xMgxSe (0 < x < 0.55) crystals grown by the high pressure Bridgman method. In the composition range investigated Cd1-xMgxSe crystallizes in a wurtzite structure while Zn1-xMgxSe crystallizes in sphelerite and wurtzite for Mg content lower and higher than 0.18, respectively. The temperature dependence of luminescence can be explained by taking into account, that statistical fluctuations of local composition in solid solutions cause spatial fluctuations of potential, leading to localization of excitons at low temperatures. This phenomenon strongly influences radiative recombination processes in such mixed semiconductors. All observed luminescence characteristics can be explained by this exciton localization model. (C) 2003 Elsevier B.V. All rights reserved.
机构:
New York State Ctr Adv Technol Photon Mat & Appli, Dept Chem, New York, NY 10031 USANew York State Ctr Adv Technol Photon Mat & Appli, Dept Chem, New York, NY 10031 USA
Guo, SP
;
Zeng, L
论文数: 0引用数: 0
h-index: 0
机构:New York State Ctr Adv Technol Photon Mat & Appli, Dept Chem, New York, NY 10031 USA
Zeng, L
;
Tamargo, MC
论文数: 0引用数: 0
h-index: 0
机构:New York State Ctr Adv Technol Photon Mat & Appli, Dept Chem, New York, NY 10031 USA
机构:
CUNY City Coll, Ctr Anal Struct & Interfaces, New York State Ctr Adv Technol Ultrafast Photon, New York, NY 10031 USACUNY City Coll, Ctr Anal Struct & Interfaces, New York State Ctr Adv Technol Ultrafast Photon, New York, NY 10031 USA
Maksimov, O
;
Guo, SP
论文数: 0引用数: 0
h-index: 0
机构:CUNY City Coll, Ctr Anal Struct & Interfaces, New York State Ctr Adv Technol Ultrafast Photon, New York, NY 10031 USA
Guo, SP
;
Tamargo, MC
论文数: 0引用数: 0
h-index: 0
机构:CUNY City Coll, Ctr Anal Struct & Interfaces, New York State Ctr Adv Technol Ultrafast Photon, New York, NY 10031 USA
机构:
New York State Ctr Adv Technol Photon Mat & Appli, Dept Chem, New York, NY 10031 USANew York State Ctr Adv Technol Photon Mat & Appli, Dept Chem, New York, NY 10031 USA
Guo, SP
;
Zeng, L
论文数: 0引用数: 0
h-index: 0
机构:New York State Ctr Adv Technol Photon Mat & Appli, Dept Chem, New York, NY 10031 USA
Zeng, L
;
Tamargo, MC
论文数: 0引用数: 0
h-index: 0
机构:New York State Ctr Adv Technol Photon Mat & Appli, Dept Chem, New York, NY 10031 USA
机构:
CUNY City Coll, Ctr Anal Struct & Interfaces, New York State Ctr Adv Technol Ultrafast Photon, New York, NY 10031 USACUNY City Coll, Ctr Anal Struct & Interfaces, New York State Ctr Adv Technol Ultrafast Photon, New York, NY 10031 USA
Maksimov, O
;
Guo, SP
论文数: 0引用数: 0
h-index: 0
机构:CUNY City Coll, Ctr Anal Struct & Interfaces, New York State Ctr Adv Technol Ultrafast Photon, New York, NY 10031 USA
Guo, SP
;
Tamargo, MC
论文数: 0引用数: 0
h-index: 0
机构:CUNY City Coll, Ctr Anal Struct & Interfaces, New York State Ctr Adv Technol Ultrafast Photon, New York, NY 10031 USA