Nanoscale architectural control and macromolecular engineering of nonlinear optical dendrimers and polymers for electro-optics

被引：154
作者：
Luo, JD [1 ]
Haller, M
Ma, H
Liu, S
Kim, TD
Tian, YQ
Chen, BQ
Jang, SH
Dalton, LR
Jen, AKY
机构：
[1] Univ Washington, Dept Mat Sci & Engn, Seattle, WA 98195 USA
[2] Univ Washington, Dept Chem, Seattle, WA 98195 USA
来源：
JOURNAL OF PHYSICAL CHEMISTRY B | 2004年 / 108卷 / 25期
关键词：
D O I：
10.1021/jp036714o
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Recent progress in developing highly efficient nonlinear optical dendrimers and polymers for high-performance electro-optic (EO) devices has been reviewed. Our efforts are focused on using nanoscale architectural control to tailor the size, shape, conformation, and functionality of NLO chromophores and macromolecules and Studying their effects on poling efficiency. The structures of these materials vary from a 3-D-shaped dendritic chromophore, multifunctional dendrimers with the center core connected to NLO chromophores and crosslinkable functional groups at the periphery, to side-chain-dendronized NLO polymers. All the poling results from these systems have shown dramatically enhanced EO properties (a factor of 2-3) compared to conventional NLO polymers.
引用
收藏
页码：8523 / 8530
页数：8
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