Reactive sulfur species: hydrolysis of β-sulfinyl esters to give a sulfenic acid in aqueous solution

被引：2
|
作者：
Ueki, Hisanori [1 ]
Chapman, Garry [1 ]
Ashby, Michael T. [1 ]
机构：
[1] Univ Oklahoma, Dept Chem & Biochem, Norman, OK 73019 USA
来源：
JOURNAL OF SULFUR CHEMISTRY | 2009年 / 30卷 / 3-4期
基金：
美国国家科学基金会;
关键词：
sulfenic acid; sulfenate; Ellman's reagent; UV-vis spectroscopy; hydrolysis; CYSTEINE THIOSULFINATE ESTER; ENZYME CATALYSIS; KINETICS; REDOX; MECHANISMS;
D O I：
10.1080/17415990902898050
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An efficient method for synthesizing the sulfenic acid derivative of 5-mercapto-2-nitrobenzoic acid in aqueous medium is described. The electronic spectrum is reported (lambda(max) = 490 nm, epsilon = 11, 600 M-1 cm(-1)).
引用
收藏
页码：287 / 292
页数：6
相关论文
共 20 条
  • [1] Steric control for the hydrolysis of dipeptide esters in aqueous solution systems
    Goto, K
    Miki, A
    Ueoka, R
    KAGAKU KOGAKU RONBUNSHU, 1999, 25 (02) : 195 - 199
  • [2] Reactive sulfur species: Kinetics and mechanism of the hydrolysis of cysteine thiosulfinate ester
    Nagy, Peter
    Ashby, Michael T.
    CHEMICAL RESEARCH IN TOXICOLOGY, 2007, 20 (09) : 1364 - 1372
  • [3] Evolution of the molar mass distribution of oat β-glucan during acid catalyzed hydrolysis in aqueous solution
    Nguyen, Hoang S. H.
    Heinonen, Jari
    Laatikainen, Markku
    Sainio, Tuomo
    CHEMICAL ENGINEERING JOURNAL, 2020, 382
  • [4] A new kinetic model on hydrolysis of sulfur mustard non-dissolved and dissolved in aqueous solution
    Dai, Xue Zhi
    Zhou, Huan
    Zhang, Hong Peng
    Zhu, Hai Yan
    Wang, Chong
    Tang, Hua Min
    Cheng, Zhen Xing
    JOURNAL OF MOLECULAR LIQUIDS, 2024, 412
  • [5] Structures, hydrolysis, stabilities of palladium(II) complexes containing biologically active ligands and species distribution in aqueous solution
    Inci, Duygu
    Aydin, Rahmiye
    JOURNAL OF MOLECULAR STRUCTURE, 2019, 1187 : 23 - 37
  • [6] Hydrolysis of phosphate esters in aqueous solution promoted by cobalt(III)-tetraamine metallohydrolases: Chromatographic and spectroscopic studies
    Bhengu, Thokoza
    Wood, Tim
    Shumane, Manelisi
    Tafesse, Fikru
    PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2019, 194 (1-2) : 87 - 101
  • [7] Reactive Sulfur Species: Kinetics and Mechanism of the Oxidation of Aryl Sulfinates with Hypochlorous Acid
    Ueki, Hisanori
    Chapman, Garry
    Ashby, Michael T.
    JOURNAL OF PHYSICAL CHEMISTRY A, 2010, 114 (04) : 1670 - 1676
  • [8] LITHIUM HYDROXIDE AQUEOUS METHANOL - MILD REAGENT FOR THE HYDROLYSIS OF BILE-ACID METHYL-ESTERS
    DAYAL, B
    SALEN, G
    TOOME, B
    TINT, GS
    SHEFER, S
    PADIA, J
    STEROIDS, 1990, 55 (05) : 233 - 237
  • [9] Role of reactive intermediates in the radiolytic degradation of Acid Red 1 in aqueous solution
    Foeldvary, Cs. M.
    Wojnarovits, L.
    RADIATION PHYSICS AND CHEMISTRY, 2009, 78 (01) : 13 - 18
  • [10] Molecular Dynamics Study of Acid-Catalyzed Hydrolysis of Dimethyl Ether in Aqueous Solution
    Liang, Xiao
    Montoya, Alejandro
    Haynes, Brian S.
    JOURNAL OF PHYSICAL CHEMISTRY B, 2011, 115 (25) : 8199 - 8206
12