Synthesis and structure of complex compound Rh(III) of (Nh4)2[Rh(NO2)3(NH3)(μ-OH)2 composition

被引：1
|
作者：
Khranenko, S. P. [1 ]
Baidina, I. A. [1 ]
Gromilov, S. A. [1 ]
机构：
[1] Russian Acad Sci, Siberian Div, AV Nikolayev Inst Inorgan Chem, Novosibirsk, Russia
来源：
JOURNAL OF STRUCTURAL CHEMISTRY | 2006年 / 47卷 / 02期
关键词：
rhodium; X-ray phase analysis; X-ray diffraction analysis; crystallochemistry;
D O I：
10.1007/s10947-006-0310-z
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The crystalline structure of a new compound Rh(III) of (NH4)(2)[Rh(NO2)(3)(NH3)(mu-OH)](2) composition has been determined. The crystallographic characteristics are H16N10O14Rh2: a = 6.3963(2) A, b = 9.3701(4) A, 3 c = 13.6646(5) A, beta = 102.266(1)degrees, V = 800.28(5) A(3), Z = 2, d(calc), = 2.432 g/cm(3). The distance Rh...Rh in the dimer is 3.200 A.
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收藏
页码：375 / 379
页数：5
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