Organophotoredox-Catalyzed Formation of Alkyl-Aryl and -Alkyl C-S/Se Bonds from Coupling of Redox-Active Esters with Thio/Selenosulfonates

被引：46

作者：

Dong, Yue ^{[1
,2
,3
,4
]}

Ji, Peng ^{[1
,2
,3
,4
]}

Zhang, Yueteng ^{[1
,2
,3
,4
]}

Wang, Changqing ^{[1
,2
,3
,4
]}

Meng, Xiang ^{[1
,2
,3
,4
]}

Wang, Wei ^{[1
,2
,3
,4
]}

机构：

[1] Univ Arizona, Dept Pharmacol, Tucson, AZ 85721 USA

[2] Univ Arizona, Dept Toxicol, Tucson, AZ 85721 USA

[3] Univ Arizona, Dept Chem & Biochem, Tucson, AZ 85721 USA

[4] Univ Arizona, BIOS Inst, Tucson, AZ 85721 USA

来源：

ORGANIC LETTERS | 2020年 / 22卷 / 24期

基金：

美国国家科学基金会;

关键词：

S BOND; DUAL CATALYSIS; CARBON-SULFUR; THIOLS; PHOTOREDOX; DISULFIDES; IODIDES; ARYLATION; RADICALS; HALIDES;

D O I：

10.1021/acs.orglett.0c03624

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A mild organophotoredox synthetic protocol for forming a C-sp(3)-S/Se bond by reacting widespread redox-active esters with thio/selenosulfonates has been developed. The power of the synthetic manifold is fueled by an unprecedented broad substrate scope and wide functional group tolerance.

引用

页码：9562 / 9567

页数：6

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